Aysegul
Tarkin
*a and
Esen
Uzuntiryaki-Kondakci
b
aDepartment of Mathematics and Science Education, College of Education, Yuzuncu Yil University, 65080, Van, Turkey. E-mail: aytarkin@gmail.com
bDepartment of Mathematics and Science Education, College of Education, Middle East Technical University, 06800, Ankara, Turkey
First published on 12th May 2017
This study aims to compare the effectiveness of case-based instruction over traditional instruction in improving 11th grade students' understanding of electrochemistry concepts, attitudes toward chemistry, chemistry self-efficacy beliefs, and motivation to learn chemistry. In total, 113 students (47 males and 66 females) from three high schools participated in this study. Two of the classes from each school were randomly assigned to be either the experimental or control group. The experimental group was instructed by case-based instruction while the control group was taught by traditionally designed instruction. The Electrochemistry Concept Test, Attitude toward Chemistry Scale, High School Chemistry Self-efficacy Scale, and Chemistry Motivation Questionnaire were applied as pre- and post-tests to students in both groups. Moreover, a feedback form was administered to students in the experimental group at the end of the study to get students' opinions about the case-based instruction. One-way Multivariate Analysis of Variance (MANOVA) revealed that case-based instruction was an effective method to improve students' understanding of electrochemistry concepts, attitude toward chemistry, and intrinsic motivation to learn chemistry. The qualitative data gathered from the feedback forms also supported the results of the inferential statistics. Students reported that chemistry lessons were more interesting and enjoyable via case-based instruction.
Another affective variable that influences students' science learning is self-efficacy (Andrew, 1998; Britner and Pajares, 2001; Kupermintz, 2002). It is defined as “people's judgments of their capabilities to organize and execute courses of action required to attain designated types of performances” (Bandura, 1986, p. 391). Students' science self-efficacy beliefs affect their tendency to engage in science learning activities, their efforts to complete them, and their persistence in working when they encounter difficulties. Students perform the science activities that they believe they are capable of doing well and avoid tasks they believe they could not do (Bandura, 1997; Britner and Pajares, 2001). Bandura (1997) proposed that self-efficacy beliefs are shaped by four main sources of information: mastery experience, vicarious experience, social persuasion, and physiological and emotional states. Mastery experiences such as working on classroom tasks and taking responsibility for learning might provide students with opportunities to be successful, thus facilitating their self-efficacy. Students interpret the results of their previous experiences with the task and develop beliefs about their capabilities. In particular, students' successful experiences in executing a task will increase their self-efficacy, while failures will decrease it (Bandura, 1997; Linnenbrink and Pintrich, 2002). Small-group work, or collaborative work, may serve as a vicarious experience. Collaboration provides students with opportunities to see how their peers approach the learning task and solve problems. In other words, group working activities allow them to learn from peers. In addition, they get explicit feedback about their performance in the task from their peers during the collaborative process, which might contribute to students' self-efficacy beliefs. Positive affirmations and social persuasion about students' capabilities to succeed in the task will increase their self-efficacy beliefs. Moreover, positive physiological and emotional states such as happiness and exhilaration are more likely to enhance self-efficacy beliefs than negative ones such as sadness and anxiety (Bandura, 1997). Because traditional instruction does not provide students with an opportunity to be actively involved in a learning task, construct their knowledge, and work collaboratively, it is not adequate for increasing students' self-efficacy beliefs.
In the small-group method, collaborative or cooperative learning strategies are used with small groups. There are four formats for small-group case-based instruction: problem-based learning, interrupted case method, intimate debate method, and team learning. Problem-based learning—widely used in training medical students—is the most popular small-group case approach. In this format, teams of students work with tutors. In addition, information is provided over several class periods and students add literature research when needed. In the interrupted case method, conversely, students deal with each case in a single class period, without literature research. Cases provide all the information and data that students use while solving the problem. The intimate debate method is effective in dealing with controversial topics such as global warming or stem cell research. Groups of students prepare points on both the pro and con sides of an issue. Then, pairs of students from each group couple with pairs of students in other groups who have opposite viewpoints on the question or issue and argue their perspectives. Next, student pairs reverse the roles. Finally, they try to reach a consensus on the question. In the final format of the small-group method, team learning, students are given a reading assignment before the class session. In the class session, students first take an individual test related to the reading material and then take the test in small groups. Both the individual and group tests are scored in the classroom immediately (Herreid, 2011).
Case-based instruction allows students to construct their knowledge and puts importance on authentic, meaningful, and active learning as proposed by the constructivist approach (Guest, 2007). It enhances students' abilities to recognize a wide range of applicable social problems and concerns, and provides them with opportunities to solve them in a collaborative environment. The role of the instructor is to provide appropriate cases and guide learning by asking appropriate questions that promote analysis, discussion, and resolution for the specific problem given in the case. This helps learners to put their theoretical knowledge into practice and to see the relevance of the subject to their life, rather than merely memorizing a prescribed body of knowledge. Moreover, case-based instruction makes the classroom environment vigorous and more engaging than traditional instruction, because students are involved in trying to put ideas into their own words when studying cases (Herreid, 2005). This method also increases retention of science learning (Cornely, 1998). In science education literature, research studies have indicated that case-based instruction enhanced students' problem solving, higher order thinking, collaboration, decision making, and critical thinking skills (Herreid, 1994, 2007; Jones, 1997; Cornely, 1998; Morrison, 2001; Rybarczyk et al., 2007) and increased achievement (Gabel, 1999; Cakir, 2002; Adali, 2005; Ozkan and Azar 2005; Rybarczyk et al., 2007; Saral, 2008; Cam, 2009; Skolnick, 2009; Morris, 2013; Yalcinkaya and Boz, 2015). Case-based instruction is likely to be effective in increasing students' attitudes toward science and their motivation because it provides opportunities for students to experience or practice real-life situations and to perceive the relevance of science. The literature provides evidence that students see case-based instructional strategies as realistic, challenging, interesting, enjoyable, and encouraging learning (Bridges and Hallinger, 1992; Wassermann, 1994; Jones, 1997; Smith and Murphy, 1998; Dori and Herscovitz, 1999; Mayo, 2002, 2004; Naumes and Naumes, 2006). However, there is little empirical research on the effect of case-based instruction on students' motivation and attitude toward science, excepting the studies conducted by Cam (2009), Saral (2008), Skolnick (2009), and Yalcinkaya (2010). Their findings indicate that case-based instruction promotes intrinsic and extrinsic motivation, and that students find the learning tasks valuable more so than students instructed with traditionally designed instruction. Still, further research is warranted to provide empirical evidence for the effect of case-based instruction on students' motivation and attitudes at different grade levels and in different branches of science. In addition, case-based instruction has potential to provide mastery and vicarious experiences by engaging students in solving authentic problems and working collaboratively, and therefore is likely to promote students' science self-efficacy beliefs (Dunlap, 2005). However, to our best knowledge, there are no studies that provide empirical evidence concerning the effectiveness of case-based instruction on students' chemistry self-efficacy beliefs.
In the present study, case-based instruction was implemented in the context of chemistry, specifically in electrochemistry topics. The relevance of electrochemistry to our life and the environment is limitless; it is tied to the batteries used in many electronic devices (e.g., mobile phones, calculators, and clocks), metal plating used in industry, photosynthesis, and respiration, which involves oxidation–reduction reactions. Moreover, electrochemistry concepts explain the process of environmental events such as acid rain, corrosion of metals, water purification by chlorination, and energy production. Regardless, electrochemistry is one of the chemistry subjects which is perceived as difficult and abstract by students (Johnstone, 1980; Finley et al., 1982; Butts and Smith, 1987; Soudani et al., 2000). Mainly, students have difficulty applying their theoretical knowledge about oxidation–reduction concepts when interpreting daily life events. Soudani et al. (2000) propose some factors that may be responsible for students' difficulties in electrochemistry: teachers' focus on algorithmic problem solving rather than students' understanding of their environment; students' unawareness of the relevance of chemistry to their life and environment; students' lack of curiosity about chemistry learning; and students' exclusive focus on getting the best grades to move up into higher classes, which directs them to rote learning rather than deep understanding of concepts. Case-based instruction might help students to understand the electrochemistry concept, since activities related to daily life events will attract students' interest in and curiosity about chemistry and increase their awareness of the relevance of chemistry to their life and environment. Thus, this kind of instruction might be effective in promoting meaningful learning of electrochemistry concepts and improving students' scientific literacy.
Problem-based instruction and case-based instruction are very similar in terms of their characteristics. For example, both approaches are student-centered and collaborative, provide an authentic context for learning, and involve discussion sessions. However, they differ from each other in many points. The main difference between these two approaches is that problem-based instruction requires more course sessions to investigate each problem than case-based instruction. In case-based instruction, each case is generally investigated in two course sessions. In addition, problem-based instruction must involve an ill-structured problem which is provided in a kind of case. However, in case-based instruction, the case is not necessarily a problem. In other words, a case can be a story including a learning message such as an article from a newspaper or an anecdote from history as well as a problem. Traditionally, students read and reflect on case questions with teachers and peers by engaging in a discussion. The discussion is the important part of the learning. In contrast, in problem-based instruction, students are provided a series of artifacts and they determine the problem and propose a solution by examining the documents. The learning is embedded in the problem solving process. Students are expected to master the course objectives while working on the problem (Bridges and Hallinger, 1992; Kain, 2003). Then, a discussion session similar to case-based instruction is followed. Moreover, case-based instruction has different types which are described in the next part. In case-based instruction, the learning environment can be individual as well as collaborative, which is the essential characteristic of problem-based instruction. In contrast to problem-based instruction, case-based instruction can be conducted with large groups by using clicker cases defined in the next part. Another difference is that problem-based learning allows students to explore the knowledge needed to understand a given phenomenon whereas CBL requires the students to have a degree of prior subject matter knowledge to solve the problem given in the case (Bridges and Hallinger, 1992; Williams, 2005; Tarnvik, 2007; Allchin, 2013).
Case-based instruction has also commonalities with context-based instruction since both of them provide learning in a context. Context-based instruction is defined as “using concepts and process skills in real-world contexts that are relevant to students” (Glynn and Koballa, 2005, p. 75). As in the case-based instruction, students learn subjects in a real-world context that allows them to make connections between the subjects and their lives. In context-based instruction, a series of case studies that are based on a real-world context was developed and related to the concepts of the chemistry curriculum (Hofstein and Kesner, 2006). Pilot and Bulte (2006) stated that “contexts are meant to explicitly relate the sciences and technology to socio-scientific issues” (p. 1088). For example, by utilizing context-based instruction, organic chemistry may be introduced in the context of materials such as plastics and polymers that are familiar to the readers. Another example is that environmental context such as acid rain may be used to teach the concepts of acids, bases, and pH (Schwartz, 2006). Similar to case-based instruction, context-based instruction allows students to see “the importance and relevance of science for themselves and the application of scientific concepts and methods” (Parchmann and Luecken, 2010, p. 2). However, in context-based instruction, a unit is taught through cases based on a particular context, which generally describes a societal problem in the real world whereas a unit can be taught by forming cases based on different contexts.
Although the related literature suggests that case-based instruction would be more effective compared to the traditional instruction, the success of any teaching instruction depends on several issues. Although, major changes in the Turkish secondary chemistry education curriculum have been taking place and implemented gradually in line with constructivism since 2007, teachers and students devalued the proposed constructivist teaching, arguing that educational circumstances in Turkey are not ready to implement it under the competitive university entrance examination system. In addition, according to the new curriculum, the role of the teacher changed from the disseminator of information to the facilitator that guides students to construct their own knowledge. Teachers think that more class time is needed for students to construct knowledge, and this presents a difficulty for them since they need to complete a topic in an allocated period of time determined by the curriculum. Since teachers in Turkey are used to teaching in a traditional way, direct instruction is still dominant in our country and it would take some time for teachers to get accustomed to their new roles. Similarly, students are used to be taught by traditional instruction. It is not clear whether all teaching methods based on constructivism would be equally successful across all subject areas and for all students (Airasian and Walsh, 1997). In addition, it is misleading to consider teaching methods such as memorization and rote-learning useless. “There are, indeed, matters that can and perhaps must be learned in a purely mechanical way.” (von Glasersfeld, 1995, p. 2). Moreover, not all aspects of a subject can or should be taught in the same way or be acquired solely through student-centered activities (Airasian and Walsh, 1997). Cobern et al. (2010) also mentioned that the nature of a topic does influence the choice of the most effective method of instruction. Due to the fact that students are accustomed to more teacher control and directions, with an emphasis on correct answers and not expressing their thought processes, it is more suitable to start constructivist teaching with case-based instruction rather than problem-based instruction. Moreover, teaching with several cases in different contexts instead of a particular context might provide more opportunity for students to see the importance and relevance of science for themselves. Therefore, we thought that it would be meaningful to compare case-based instruction with traditional instruction in order to reveal which one would be more effective for the students in our country in the context of the electrochemistry topic.
Based on the literature review and the information above about the use of case-based instruction, the following research questions were created for this study in order to reveal the effects of case-based instruction on students learning and other salient variables affecting learning.
(1) Is there a significant mean difference between the groups exposed to case-based instruction and traditionally designed chemistry instruction with respect to understanding of the electrochemistry concept, attitudes toward chemistry, chemistry self-efficacy beliefs, intrinsic motivation, and perception about relevance of chemistry to personal goals at the 11th grade level?
(2) What are 11th grade students' views about case-based instruction, based on the reactions of the participants?
Groups | Pre-tests | Treatment | Post-tests |
---|---|---|---|
Note: EG: experimental group, CG: control group, ECT: Electrochemistry Concept Test, ASTC: Attitude Scale toward Chemistry, CMQ: Chemistry Motivation Questionnaire, HCSS: High School Chemistry Self-Efficacy Scale. | |||
EG | ECT | Case-based instruction | ECT |
ASTC | ASTC | ||
CMQ | CMQ | ||
HCSS | HCSS | ||
CG | ECT | Traditional instruction | ECT |
ASTC | ASTC | ||
CMQ | CMQ | ||
HCSS | HCSS |
Cases | Descriptions | Concepts of electrochemistry |
---|---|---|
(1) Gold goods | The case presents a dialog between two cousins watching a TV program. The program introduces a house containing gold goods. Based on the program, the two cousins start to talk about those gold materials in terms of whether they are completely made of gold or electroplated by gold. They share their knowledge about the process of electroplating materials by gold with each other. | Faraday's law and the relationship among redox reaction, electric current and material changes. |
(2) Silver materials | This case describes a dialog which takes place between two girls namely Brenda and Sindy. They are talking about their silver jewellery and the problem of silver tarnish. | Redox reactions, oxidation, and reduction |
(3) Accumulators | It describes an event that occurred while two families were having a trip in their cars. They stayed at an isolated and uninhabited place for two days. At the end of their trip, one of the cars didn’t start because of low battery voltage. There were no repair shops and residents around. | Working principles of rechargeable batteries and accumulators, galvanic cell, electrode, and half-cell |
(4) Roentgenograms for source of money | It introduces the idea of making money by removing silver from old roentgenograms with the purpose of teaching electrolysis and the industrial application of it. | Industrial applications of electrochemistry and electrolysis |
(5) Fruit clocks | It presents a story about a fruit clock. In the story, a girl buys a clock that worked with fruits as a present for her brother. The girl and her brother set up the clock by looking at the user guide of the clock and talk about the working principle of it. | Electrochemical cell, electrode, and half-cell |
(6) Clean energy | The case introduces news related to cars working with hydrogen fuels. | Industrial applications of electrochemistry and fuel cell |
(7) Recycling gold from electronic waste | The case provides some information about the amount of electronic waste in Turkey and the amount of valuable metals obtained from electronic waste. Furthermore, it focuses on works of the Ministry of Environment and Forestry on the recycling process of electronic waste. | Industrial applications of electrochemistry and electrolysis |
(8) Bridge | It presents a story about a bridge collapse in a river. | Corrosion and the protection methods of it |
Before the treatment the researcher formed small groups of five or six students in the experimental group from each school. The groups were formed based on the distribution of z-scores calculated from students' standard scores on pre-tests. The researcher aimed to form heterogeneous groups as much as possible in terms of students' chemistry achievement, attitude toward chemistry, and motivation to learn chemistry as determined by the pre-ECT, pre-ATCS, and pre-CMQ, respectively. Before the treatment, the teacher announced that the students would learn the electrochemistry topic by a new method called case-based instruction.
She provided information about the method, explaining what it is and how it is applied in classroom settings and emphasizing the roles of the students in detail.
A sample case used in the experimental groups (Silver Materials) is given in Appendix B. It describes how silver jewellery can be cleaned with a hot sodium bicarbonate solution and aluminium foil. This case was used to teach how to identify reducing and oxidizing agents in a redox reaction and how to balance redox in this case to the groups. Then, two of the students read the case to the whole class. Afterwards, each group analyzed the case and answered six questions given at the end of the case by discussing their answers with their group members. After the discussion, each group wrote down their answers. The questions were:
(1) Why do silver materials tend to lose their brightness and tarnish overtime? Could you write the chemical reaction equations that explains this situation? What are the oxidizing and reducing agents? Write oxidation and reduction half reactions.
(2) Do you think that we could polish our silver goods? Do an experiment to polish one of your silver goods.
(3) Could you write the chemical reaction equations that explain the process of polishing silver jewellery? What are the oxidizing and reducing agents? Write their half reactions.
(4) What is the function of sodium bicarbonate solution used during the cleaning process of silver jewellery? Is it important to use hot sodium bicarbonate solution? If yes, why?
(5) Why is aluminium foil used during the cleaning process of silver jewellery? Can you use another material instead of aluminium foil?
(6) Green color is produced on the surface of copper materials over time. What might be the reason for this situation? Could you write the chemical reaction equation that explains this situation? What are the oxidizing and reducing agents? Write their half reactions.
After each group answered the first question, the teacher asked them to share their answers and discuss as a class. Five minutes of discussion time were given to the students to argue how silver is tarnished, which chemical reaction occurs, and what the reducing and oxidizing agents are. Then, each group was provided with the necessary equipment and they tried to clean a tarnished silver material by employing the process explained in the case. After that, each group was asked to explain the chemical process underlying the cleaning of tarnished silver materials, to write a balanced chemical reaction equation, and to identify reducing and oxidizing agents in the reaction. Each group first wrote their answers on the paper. After finishing their answers, one of the students wrote his/her group's answers on the blackboard and explained the related chemical process. Then, the other groups discussed the answer under the guidance of the teacher and explained their answers. When necessary, the teacher provided clues to help the students answer the questions. Discussion continued until the right balanced chemical reaction equation, oxidizing and reducing agents, and half reactions were decided. Regarding the fourth and fifth questions, the students examined the cleaning process in terms of the materials used (i.e., sodium bicarbonate solution, hot water, and aluminium foil). Each group was asked what the functions of these materials were during the cleaning process. In addition, they were asked whether another material could be used instead of aluminium foil. After each group finished writing their answers, group answers were shared with the class and discussed. Finally, each group tried to answer the sixth question. Regarding this question, each group expressed their ideas about why copper materials turn green over time and which chemical reaction causes this situation. The whole class discussion continued until reaching a consensus under the teacher’s guidance. At the end of the lesson, the students worked to balance several chemical reaction equations given by the teacher. For implementation of this case, the teachers were provided an instructional guide given in Appendix C.
On the other hand, in the qualitative analysis, the data gathered from feedback forms were analyzed inductively. That is, the researcher built patterns, categories, or themes from the data by generating codes and organizing them (Creswell, 2007). Students' written responses on feedback forms for case-based instruction were categorized under three headings: students' description of case-based instruction, students' perceptions about the effectiveness of case-based instruction, and the difficulties students encountered during case-based instruction. The codes subsumed under each category are presented in Table 3.
Categories | Codes | Sample excerpts |
---|---|---|
Students' descriptions of case-based instruction | Real-life issues | [It is] teaching the topic by giving examples related to the use of it in real life. |
Doing an activity/experiment | Experiments and observations are the hearth of the instruction. | |
Working in a group | We worked in groups. The cases were discussed and experiments were done when necessary. | |
Dealing with a case | A text was distributed and then we discussed our opinions related to case given in the text with our teachers. | |
Student-centered method | This instruction made us use our knowledge, think about situations, and find answers by ourselves. | |
Students' perceptions about effectiveness of case-based instruction | Learning | Learning theoretical knowledge through daily life examples enhances our learning. |
(i) Effective | Case-based instruction is not effective. In my view, ordinary instructions are more effective and easier. | |
(ii) Ineffective | ||
Enjoyment | Learning the place of chemistry in our lives was the feature that I liked most. Case-based instruction is more interesting than the instruction in the previous chemistry lesson. | |
Difficulties students encountered during the case-based instruction | No difficulty | I did not encounter any difficulties. |
Working in a group | Working in a group was not for me, I prefer individual working, I am more concentrated when I study alone than when I work in a group. | |
Interpreting the cases | We had difficulties since we didn’t have sufficient knowledge about the cases. | |
Answering the questions | It was difficult to give an answer to the questions without knowing the topic. | |
Adopting the method | I am not used to be[ing] taught by case-based instruction. Therefore, I couldn’t adapt myself to this method. |
Treatment | Dependent variable | Mean | Std. deviation | Max | Skewness | Kurtosis |
---|---|---|---|---|---|---|
Experimental group | Understanding of electrochemistry | 4.58 | 2.35 | 9.00 | −0.029 | −1.16 |
Attitude toward chemistry | 2.82 | 0.749 | 4.73 | 0.351 | −0.072 | |
Intrinsic motivation | 2.69 | 0.690 | 4.33 | 0.231 | −0.097 | |
Relevance of learning chemistry | 2.89 | 0.888 | 4.80 | 0.195 | −0.644 | |
Self-efficacy for cognitive skills | 4.95 | 1.29 | 7.90 | 0.019 | −0.117 | |
Self-efficacy for chemistry laboratory work | 4.16 | 1.91 | 8.00 | −0.088 | −0.935 | |
Control group | Understanding of electrochemistry | 4.44 | 2.47 | 9.00 | −0.177 | −0.917 |
Attitude toward chemistry | 2.84 | 0.744 | 4.60 | 0.169 | −0.676 | |
Intrinsic motivation | 2.67 | 0.762 | 4.50 | 0.115 | 0.088 | |
Relevance of learning chemistry | 2.95 | 0.896 | 4.40 | −0.400 | −0.764 | |
Self-efficacy for cognitive skills | 4.89 | 1.33 | 8.10 | −0.159 | 0.409 | |
Self-efficacy for chemistry laboratory | 4.12 | 1.80 | 8.50 | 0.037 | −0.823 |
Treatment | Dependent variable | Mean | Std. deviation | Max | Skewness | Kurtosis |
---|---|---|---|---|---|---|
Experimental group | Understanding of electrochemistry | 15.27 | 4.96 | 25.00 | −0.090 | −0.624 |
Attitude toward chemistry | 3.17 | 0.616 | 4.33 | −0.146 | −0.295 | |
Intrinsic motivation | 2.96 | 0.621 | 4.33 | 0.009 | −0.259 | |
Relevance of learning chemistry | 3.01 | 0.769 | 4.80 | 0.076 | −0.139 | |
Self-efficacy for cognitive skills | 5.39 | 1.09 | 7.80 | 0.023 | −0.438 | |
Self-efficacy for chemistry laboratory | 5.05 | 1.81 | 9.00 | −0.410 | −0.035 | |
Control group | Understanding of electrochemistry | 12.96 | 3.50 | 21.00 | −0.157 | −0.637 |
Attitude toward chemistry | 2.84 | 0.614 | 3.93 | −0.348 | −0.128 | |
Intrinsic motivation | 2.61 | 0.633 | 4.00 | −0.306 | −0.081 | |
Relevance of learning chemistry | 2.83 | 0.844 | 4.80 | −0.114 | 0.359 | |
Self-efficacy for cognitive skills | 4.86 | 1.01 | 7.70 | 0.326 | 0.003 | |
Self-efficacy for chemistry laboratory | 3.72 | 1.81 | 8.17 | 0.744 | 0.181 |
Effect | Value | F | Df | Error df | Sig. | Partial eta squared | Observed power | |
---|---|---|---|---|---|---|---|---|
Treatment | Pillai's Trace | 0.172 | 3.678 | 6 | 106 | 0.002 | 0.172 | 0.949 |
Wilks' Lambda | 0.828 | 3.678 | 6 | 106 | 0.002 | 0.172 | 0.949 | |
Hotelling's Trace | 0.208 | 3.678 | 6 | 106 | 0.002 | 0.172 | 0.949 | |
Roy's Largest Root | 0.208 | 3.678 | 6 | 106 | 0.002 | 0.172 | 0.949 |
The results revealed that there was a statistically significant mean difference between the experimental and control groups with respect to combined dependent variables of understanding of electrochemistry, attitude, intrinsic motivation, perceptions regarding relevance of learning chemistry to personal goals, and self-efficacy for cognitive skills and chemistry laboratory work after the treatment: F(6,106) = 3.678, p < 0.05; Wilks' Lambda = 0.828. The value of partial eta squared based on Wilk's Lambda, 0.172, indicated that the magnitude of the difference between the experimental and control groups was not small. In other words, it means that 17.2% of the multivariate variance of the dependent variables could be explained by the treatment. The value of power, another important statistic, was found to be 0.949. These findings implied that the difference between the experimental and control groups arose from the treatment effect and that this difference had practical value.
Given the significance of the overall test, the univariate main effects (tests of between-subjects effects) were examined by a follow-up ANOVA. Before interpreting the result of the ANOVA, the assumption of equality of variances was checked. The result of Levene's test is displayed in Table 7.
F | df1 | df2 | Sig. | |
---|---|---|---|---|
Understanding of electrochemistry | 10.354 | 1 | 111 | 0.002 |
Attitude toward chemistry | 0.405 | 1 | 111 | 0.526 |
Intrinsic motivation | 0.018 | 1 | 111 | 0.894 |
Relevance of learning chemistry | 0.128 | 1 | 111 | 0.721 |
Self-efficacy for cognitive skills | 0.490 | 1 | 111 | 0.485 |
Self-efficacy for chemistry laboratory | 0.195 | 1 | 111 | 0.660 |
The results of Levene's test showed that each dependent variable had the same variance across groups with a significance value higher than 0.05, except for understanding of electrochemistry. Since this assumption was not met for one of the dependent variables, a more conservative critical level (0.04) was set for determining significance for that variable in the univariate F-test rather than the conventional 0.05 level (Tabachnick and Fidell, 2007). The results of follow up ANOVA were interpreted by using a Bonferroni adjusted alpha level in order to avoid Type 1 error, because a number of separate analyses would be considered (Field, 2013). For this purpose, the original alpha level of 0.04 was divided by the number of dependent variables, which was six, and the new alpha level was set as 0.0067. The follow up ANOVA using a Bonferroni adjusted alpha level of 0.0067 yielded three significant main effects for the instructional strategies on dependent variables (see Table 8).
Source | Dependent variable | F | Sig. | Partial eta squared | Observed power |
---|---|---|---|---|---|
Treatment | Understanding of electrochemistry | 8.026 | 0.005 | 0.067 | 0.802 |
Attitude toward chemistry | 7.849 | 0.006 | 0.066 | 0.793 | |
Intrinsic motivation | 8.443 | 0.004 | 0.071 | 0.821 | |
Relevance of learning chemistry | 1.468 | 0.228 | 0.013 | 0.225 | |
Self-efficacy for cognitive skills | 7.035 | 0.009 | 0.060 | 0.748 | |
Self-efficacy for chemistry laboratory | 7.455 | 0.007 | 0.063 | 0.772 |
One of the significant mean differences was observed in the students' understanding of electrochemistry: F(1,111) = 8.026, p < 0.0067. The mean scores on the electrochemistry concept post-test indicated that the students in the experimental group had significantly higher mean scores (M = 15.271, SD = 4.961) than those in the control group (M = 12.963, SD = 3.502). Another significant mean difference was found between experimental and control groups with respect to students' attitudes towards chemistry: F(1,111) = 7.849, p < 0.0067. The mean scores on the attitude toward chemistry scale indicated that students in the experimental group had significantly higher scores (M = 3.168, SD = 0.616) than those in the control group (M = 2.843, SD = 0.614). Finally, the results of the follow-up ANOVA indicated that there was a statistically significant mean difference between the experimental and control groups in terms of students' intrinsic motivation in chemistry: F(1,111) = 8.443, p < 0.0067. The students in the experimental group had a significantly higher mean score of intrinsic motivation (M = 2.957, SD = 0.621) than those in the control group (M = 2.614, SD = 0.633). The values of partial eta squared were found as 0.067, 0.066, and 0.071 for understanding of electrochemistry, attitude toward chemistry, and intrinsic motivation respectively. These values indicated that approximately 7% of multivariate variance of these dependent variables was associated with the treatment. The values of power were found as 0.802, 0.793, and 0.821 for understanding of electrochemistry, attitude toward chemistry, and intrinsic motivation respectively. These findings implied that the difference between the experimental and control groups arose from the treatment effect and had practical value.
On the other hand, although students in the experimental group had a higher mean score on the relevance of learning chemistry to personal goals (M = 3.013, SD = 0.769) than those in the control group (M = 2.830, SD = 0.844), the mean difference between the groups was not significant: F(1,111) = 1.468, p > 0.0067. In addition, there was no statistically significant mean difference between the experimental and control groups in terms of students' chemistry self-efficacy for cognitive skills (F(1,111) = 7.035, p > 0.0067) and self-efficacy for chemistry laboratory work (F(1,111) = 7.455, p > 0.0067). However, the mean score of the experimental group on these dependent variables was higher than the control group.
Briefly, as can be seen from Table 5, the mean score of the experimental group on each dependent variable was higher than that of the control group; but only the scores on the electrochemistry concept test, attitude toward chemistry, and intrinsic motivation were significant.
Another key element of case-based instruction as stated by the students was doing an activity/experiment (47.1%). One of the students emphasized the importance of the activities in case-based instruction as “Experiments and observations are the hearth of the instruction.” Another student thought that it was the experiments that helped them learn the topic. The students also made a connection between the cases and the experiments, based on the following excerpt: “We explained cases considering the results of experiments.” Besides working on daily life issues and doing experiments, the students pointed to working in a group (27.9%) and dealing with a case (25%) as other characteristics of case-based instruction. The clearest feedback for this category was detailed and accurate:
[During the instruction], groups were formed. A text was distributed and then we discussed our opinions related to the case given in the text with our teachers and did experiments.
Another student explained that “We worked in groups. The cases were discussed and experiments were done when necessary.”
Some of the students concluded that case-based instruction was a student-centered method. For instance, it was stated that “It provided us with an opportunity to express our opinions and thoughts.” Likewise, some students emphasized their efforts during class to find the knowledge they needed to explain the case. For example, one of the students wrote that “All students were actively involved in learning activities by observing and doing.” Another student expressed that “This instruction made us use our knowledge, think about situations, and find answers by ourselves.” These ideas supported students' view of case-based instruction as student-centered instruction.
In summary, the students viewed case-based instruction as a student-centered teaching method including implementation of an activity/experiment, working in a group, and dealing with real-life examples.
Case-based instruction is an effective method because visual examples/materials are permanent/long-lasting in the mind. Learning through visuals provides meaningful learning instead of rote learning. When we see similar situations, we can make a logical interpretation by figuring out the previous case in our minds.
In addition, the students expressed their ideas about the effectiveness of incorporating daily life events and using visuals on chemistry learning by comparing their previous instruction with the case-based instruction: “Beforehand, knowledge was presented directly not by cases and therefore, understanding chemistry was quite difficult. Now, both observing and relating the topics with real-life events are more helpful for us to understand the topic.” They emphasized the benefit of cases in their learning; the cases help them realize the importance of studying chemistry:
Beforehand, when formulas and names of the compounds were written on the board, none of the examples emerged in my mind. There was no explanation about why we were doing/learning this. However, this method makes chemistry more illuminating for me since it teaches chemistry by providing cases and using visual materials. It teaches not only formulas for university exams but also chemistry which we need in our lives.
Furthermore, some students stated that they learned the chemistry topics easily through case-based instruction. For example, one of the students started to think that chemistry was not difficult any more. S/he stated that “We primarily understood that chemistry can be learned.” Conversely, a few students (9%) thought that the case-based instruction was ineffective because they were not used to being taught that way and doing activities without knowing the topic. For example, one student stated that “In my opinion, case-based instruction is not an effective method since the instruction by which we were taught for years required rote learning (and we want to get knowledge directly).” Similarly, another one expressed that “Case-based instruction is not effective. In my view, ordinary instructions are more effective and easier.”
Regarding enjoyment, 40.3% of the students indicated that the case-based instruction was interesting and enjoyable. For instance, one student stated that “Chemistry lessons became livelier and less boring due to experiments and reading texts/cases. I learned chemistry in this class better than in previous lessons.” Similarly, another student thought that “Chemistry became more enjoyable through case-based instruction.” Generally, students described case-based instruction as amusing, enjoyable, and interesting. One also expressed that “It increases our interest in chemistry since it answers the question: where do we use this chemistry knowledge in our lives?” One of the reasons students find case-based instruction enjoyable is that they realize the relationship between chemistry and real life. For instance, one of the students stated that “Lessons were more enjoyable. My interest to chemistry increased. I performed some experiments at home. I tried to clean my tarnished silver ring (lemon juice, carbonate) and I succeeded. I liked it very much. I understood that chemistry is embedded in our lives.” Another student also expressed a similar idea: “the feature of case-based instruction that I liked most was its emphasis on the relationship between chemistry and our lives; and thus we understand the importance of chemistry in our life. Thus, my interest in chemistry learning increased.” Some students highlighted that their attitude toward chemistry improved, as can be concluded from the following statement: “Learning the place of chemistry in our lives was the feature that I liked most. Case-based instruction is more interesting than the instruction in the previous chemistry lesson. I liked chemistry a bit more.” Students also enjoyed the active learning process: “I enjoyed the lesson because the teacher and the students draw conclusions together during the lesson. In addition, making us think and draw conclusions based on our previous knowledge was good.”
In my opinion, previous lessons were more effective. From primary school to now, teachers transferred knowledge to us directly without conducting any experiments. Learning is easier since we were accustomed to learn in that way. I had difficulty in interpreting cases and observations during experiments.
Another student considered the experience as similarly problematic:
I certainly had difficulties because I hadn't been taught with this method before. Since I didn't know what I would do exactly I found it difficult at the beginning. Probably, I am not used to be[ing] taught by case-based instruction. Therefore, I couldn't adapt myself to this method. I thought that I didn't learn well. However, I overcame my deficiencies by my own effort.
Students who were taught by case-based instruction demonstrated significantly higher scores on the electrochemistry concept test than those who were taught traditionally. In other words, this study indicated that the case-based instruction was more effective than traditional instruction in terms of promoting meaningful understanding of electrochemistry concepts. Therefore, the current study provides further empirical support for the previous studies in science education showing the effectiveness of case-based instruction over traditional instruction (e.g., Cakir, 2002; Ozkan and Azar, 2005; Rybarczyk et al., 2007; Saral, 2008; Cam, 2009; Skolnick, 2009; Morris, 2013; Yalcinkaya and Boz, 2015). The probable underlying reasons that the case-based instruction was effective in improving students' understanding of electrochemistry concepts can be tied to the characteristics of the instruction. Leonard (2000) pointed out that when students are actively involved (physically, emotionally, and mentally) in a learning process, they will have a deeper understanding of concepts and retain that understanding longer than when the learning experience is passive. In the literature, it is clear to science educators that active learning environments based on a constructivist approach have a crucial impact on students' meaningful learning (Barron et al., 2008; Duit and Treagust, 1998; Mayer, 1999). In the experimental group of this study, the case-based instruction created an active learning environment that involved students in solving and examining real-world problems in small groups with guided instruction. Small group and whole class discussions directed the students to think about the situations and encouraged them to express their ideas. Thus, the case-based instruction allowed the students to construct their knowledge in an authentic and active learning environment. On the other hand, the students in the control group were passive during their traditional chemistry instruction. The knowledge was transmitted from the teacher to the students. The active learning environment during the case-based instruction may have provided the students with better understanding of electrochemistry concepts compared to traditional instruction.
Furthermore, dealing with real-life examples might have played a role in the difference between the experimental group and control group students' acquisition of the concepts. The learning tasks that emphasize the relevance and meaningfulness of the content promote students' interest in learning and thus enhance students' learning (Kortland, 2007). In this study, the content of the cases reflected daily life situations, which helped students gain an insight into the role of chemistry in their life and thus see the importance and relevance of it for themselves. Students in the experimental group also stressed on the feedback form that visual materials, experiments, and daily life examples were helpful in learning chemistry because those tools allowed them to create links to real life instead of focusing on simple memorization. In addition, the use of cases during instruction helped them realize the importance of chemistry learning. In general, electrochemistry is one of the chemistry subjects perceived as difficult by students (Johnstone, 1980; Finley et al., 1982; Butts and Smith, 1987; Soudani et al., 2000). Soudani et al. (2000) proposed that one of the factors responsible for students' difficulties in electrochemistry was their unawareness of the relevance of chemistry to their life and environment. Students generally see the scientific facts, definitions, and formulas as school knowledge and memorize them just to pass their chemistry exams. They do not see the importance and relevance of learning chemistry concepts for themselves (Hutchinson, 2000). However, for meaningful learning it is suggested that the learning material should be relevant to students' lives; when this is the case, students view the content they are learning as useful and learn the topic more meaningfully (Ames, 1992; Zusho et al., 2003; Glynn et al., 2007). Regarding this point, the present study reveals that the case-based instruction provided an effective learning environment that increases students' attention and helps them see the relevance and importance of chemistry to their lives (rather than merely memorizing a prescribed body of knowledge) and thus enhances their understanding of the topic.
The present study provided empirical evidence for the positive effect of case-based instruction not only on chemistry learning but also on the development of positive attitudes toward chemistry as a school subject. This result is parallel with the findings of other studies that utilized case-based instruction to promote students' attitudes toward science, such as Cam (2009), Cakir (2002), Ozkan and Azar (2005), Gallucci (2007), and Yalcinkaya (2010). In addition, analysis of students' written responses on the feedback form also supported this result—the students instructed with the case-based instruction reported positive opinions about the chemistry lesson and chemistry learning, and they found chemistry lessons more interesting and enjoyable via case-based instruction when compared to their previous traditional chemistry instruction. In addition, they pointed out that realizing the importance and the relevance of chemistry to their lives increased their interest in learning chemistry. This finding supported the fact that the relevance and authenticity of the topics being studied is one of the factors influencing students' attitudes toward science, as stated by Raved and Assaraf (2011) and Movahedzadeh (2011). In general, the findings of the present study supported the results of previous studies that revealed that the students find case-based instruction realistic, challenging, interesting, enjoyable, and encouraging for learning (Bridges and Hallinger, 1992; Wassermann, 1994; Jones, 1997; Smith and Murphy, 1998; Dori and Herscovitz, 1999; Mayo, 2002, 2004; Naumes and Naumes, 2006; Herreid, 2007; Ayyildiz and Tarhan, 2012). The case-based instruction provided opportunities for the students to experience and practice real life situations and thus perceive the relevance of science. Since chemistry is seen as a boring subject and irrelevant to life (Hutchinson, 2000; Soudani et al., 2000), case-based instruction is more likely to contribute to an increase in student interest in chemistry and improve their views about the relevance of chemistry to their lives, which enhances their attitudes toward chemistry. The literature indicated that active participation of students in the learning process is also a main characteristic of effective instructions that promote a positive attitude toward science (Fouts and Myers, 1992; Wong et al., 1997; Oliver-Hoyo and Allen, 2005). Since the students instructed using the case-based instruction were provided with opportunities to be actively involved in and take responsibility for their learning, they might have had more positive attitudes toward chemistry compared to students taught traditionally.
Regarding the motivation variable, after the treatment the students instructed by the case-based instruction had higher intrinsic motivation to learn chemistry than those taught traditionally as concluded from both MANOVA results and written responses. These findings are inconsistent with some of the results of previous studies conducted in science education. For example, Yalcınkaya (2010) investigated the effectiveness of case-based instruction on students' motivation in chemistry. The results of her study revealed that there was no significant mean difference in students' perceived intrinsic motivation. Similarly, a study by Saral (2008) detected no significant mean difference in students' perceived intrinsic motivation in biology after case-based instruction, although their scores were higher than those of students taught traditionally. Opposite to those results, the present study provides empirical evidence for the effectiveness of case-based instruction on students' motivation to learn science, particularly chemistry. The case-based instruction provided opportunities for the students to deal with cases involving authentic examples. This characteristic of case-based instruction may have increased students' curiosity and interest, thus the students in the experimental group were more inherently motivated to learn chemistry than those in the control group. Moreover, Herreid (2005) stated that case-based instruction makes the classroom environment vigorous and more engaging than traditional instruction because students are involved in trying to put ideas into their own words while studying cases. Students are intrinsically motivated when they engage in activities (Wigfield et al., 1998). In the literature, in addition to the relevance of the content to one's life, encouraging students' active participation in the learning process through small group work activities or leading discussions is seen as useful for promoting motivation to learn (Ryan and Deci, 2000; Linnenbrink and Pintrich, 2002; Glynn and Koballa, 2006; Kusurkar et al., 2011; Vaino et al., 2012). Due to the fact that the students instructed with case-based instruction worked in small groups and discussed their ideas with group members and the whole class, this kind of learning environment might have increased their intrinsic motivation at the end of the treatment.
Surprisingly, the results of the study demonstrated no significant effect of the case-based instruction on students' perceptions regarding relevance of learning chemistry to personal goals compared to traditional chemistry instruction. In other words, there was no significant difference between experimental and control groups in terms of their willingness to engage in chemistry learning for reasons such as their future careers, goals, and lives. One of the reasons for this non-significant result might be the limited implementation period of the case-based instruction. Seven weeks might not be enough to significantly change students' perceptions about the relevance of learning chemistry to their personal goals. In addition, implementation of the case-based instruction was limited to one unit (electrochemistry) in the high school chemistry curriculum. It is difficult to consider all students' future goals and careers while designing the case-based instruction only on the topic of electrochemistry. In this study, the topics of the cases differed from each other. Therefore, the topics of the cases might not have all been related to students' future goals, or one related topic might not be sufficient for students to relate chemistry learning to their future careers. Designing the case-based instruction based on students' interests and future goals might be more effective in promoting their perceptions regarding the relevance of learning chemistry to their personal goals. In addition, having a longer implementation period of case-based instruction on different topics of chemistry may yield greater change in students' perceptions. Still, although we could not find a statistically significant difference, it is interesting to note that students' perceptions about the relevance of learning chemistry decreased after receiving traditional instruction for the topic of electrochemistry, while they increased after the case-based instruction.
Regarding the last affective variable of the study, no significant mean difference was detected in either students' self-efficacy for cognitive skills or for chemistry laboratory work across the experimental and control groups after the treatment. However, it is worthwhile to say that in both these categories the scores of the students instructed with the case-based instruction were higher than those instructed traditionally. One of the possible reasons for this result might again be related to the short duration of the treatment. Since many authors have argued that beliefs are highly resistant to change (Bandura, 1986, 1997; Pajares, 1992), the limited period of implementation of case-based instruction might not have been sufficient for the students to improve their chemistry self-efficacy beliefs. Having more time for implementation of case-based instruction on various chemistry topics may result in greater changes in students' chemistry self-efficacy. Moreover, although students in the experimental group did some experiments, observed demonstrations, and reported and discussed their results during the case-based instruction, the instruction was not completely based on laboratory activities. This might be one reason for not determining a significant rise in the students' self-efficacy for chemistry laboratory work.
This study has several implications for chemistry educators and researchers. In the literature, it is clear that the nature of chemistry instruction has an important role in promoting students' meaningful learning. Instructions based on a constructivist approach emphasizing active learning are more effective in promoting meaningful learning than traditional instruction. In terms of effective chemistry teaching, although many researchers have already designed various instructional strategies providing active learning environments and explored their effects on students' learning, new teaching methods are still within chemistry educators’ interest. Case-based instruction, as a student-centered method, encourages students to involve themselves in the learning process actively through working on cases. Based on the findings presented in this study, case-based instruction offers a more effective learning environment than traditionally designed chemistry instruction. Therefore, this study can serve as a guide to chemistry teachers in designing effective chemistry instruction, particularly on the topic of electrochemistry.
Chemistry educators do not only deal with students' performance in the cognitive domain, but also put emphasis on students' development in the affective domain. Affective variables such as attitude and motivation impact students' learning. Chemistry lessons should be enjoyable and interesting to encourage students to improve their attitude toward chemistry and motivation to learn chemistry. In light of the findings of this study, chemistry teachers can use case-based instruction in their classes to improve students' attitudes toward chemistry and their intrinsic motivation to learn the subject. Due to the fact that students found the real-life events presented during the case-based instruction effective, enjoyable, and interesting, chemistry teachers should enrich their instructions with real-life context to improve students' learning, attitude toward chemistry, and motivation to learn chemistry.
Finally, future researchers might explore the effects of case-based instruction on students' learning in other chemistry subjects, or on other variables (such as higher order thinking and problem-solving skills) to broaden findings related to the effectiveness of case-based instruction. In addition, qualitative studies can be conducted in order to explore the effect of case-based instruction on students' chemistry learning, attitude toward chemistry, motivation to learn chemistry, and chemistry self-efficacy beliefs. In this study, implementation of case-based instruction, including real-world application, group work, and discussion, was found to be more effective than traditional instruction. In other words, the synergistic effect of dealing with real-life events, working in a group, and discussing ideas as a class enhanced students' learning, attitudes toward chemistry, and motivation to learn chemistry. However, it is uncertain which of these particular characteristics of the case-based instruction influenced students. Therefore, in future studies, some of the characteristics of the case-based instruction, such as group work, could be isolated and their influence on students' learning, attitudes toward chemistry, and motivation to learn chemistry could be examined. Moreover, further studies may investigate the effectiveness of using cases in various forms: as an in-class activity, out of class assignment, or an online assignment.
(A) Zn gives electrons.
(B) The standard reduction potential of the Zn electrode is higher than the standard reduction potential of the Cr electrode.
(C) If you want to make a galvanic cell from Zn and Cr electrodes, the Zn electrode should be placed on the left side of the cell.
(D) Oxidation reaction takes place at the Cr electrode.
(E) Zn is a stronger oxidizing agent.
(2) Ege likes a project called “Silver Tree” that he saw during a science festival event which he attended. In this project, a tree prepared using copper wire was immersed in a silver nitrate solution and the following image was obtained.
Which of the following statements describes this situation?
(A) When the copper passes through the solution by reducing, the silver ions in the solution are oxidized to metallic form on the copper wire.
(B) As the copper passes through the solution by oxidizing, the silver ions in the solution are reduced to metallic Ag on the copper wire.
(C) Copper oxidizes silver by acting as a cathode.
(D) Copper has formed a complex with silver.
(E) The reaction is Cu(s) + AgNO3(aq) → Cu(NO3)(aq) + Ag(s) + 2e−
(3) In the chemistry lab course, Sibel needs to set up an experiment to cover a copper material with silver. Sibel has the following materials. Which materials should Sibel connect to the poles of the battery and which solutions should she use in order to set up the experiment correctly?
Sibel has the following materials: copper material to be coated (Cu), silver bar (Ag), 0.1 M Cu (NO3)2 solution, and 0.1 M AgNO3 solution
1 | 2 | 3 | 4 | 5 | |
---|---|---|---|---|---|
(A) | Ag | Cu | Cu(NO3)2 | − | + |
(B) | Ag | Cu | Cu(NO3)2 | + | − |
(C) | Ag | Cu | AgNO3 | + | − |
(D) | Cu | Ag | AgNO3 | + | − |
(E) | Cu | Cu | AgNO3 | − | + |
(4) Pipelines, ships, bridges, tanks, chemical containers, reinforced concrete bars, water pipes, refineries and oil pipelines can be protected from corrosion by cathodic protection. In order to protect an underground gasoline tank made from iron from corrosion, which of the following metals cannot be put in the place shown by the question mark?
(A) Mg
(B) Ni
(C) Al
(D) Zn
(E) Cu
(5) Which of the following statements about the event shown below is true?
(A) Fe atoms in the key are reduced by taking electrons from the power source.
(B) The mass of the copper rod increases over time.
(C) The Cu+2 ions in the solution are collected on the copper rod by taking electrons.
(D) Copper atoms accumulate on the iron key over time.
(E) The copper rod acts as a cathode.
(6) In some of the experiments listed below, which iron nail or nails rust after a while?
(A) Only I
(B) Only II
(C) Only III
(D) I and III
(E) I, II and III
Brenda: I do not have any silver jewelry, but we have silver items at home, and the bright, shiny surface of them gradually darkens and becomes less shiny over time.
Sindy: Do you know why it turns dark?
Brenda: No, I do not know.
Sindy: What do you do when your silver items get dark?
Brenda: There is a shop selling silver items. We take them to the shop and make them shiny again.
Sindy: How is it cleaned? Will my silver jewelry be cleaned and shiny like new?
Brenda: Of course, your jewelry will also shine. If you want, we can go to the shop where we polish our silver items.
Sindy: Yes, I'd like to go very much. Yippee, my silver jewellery will shine like new again.
(Brenda and Sindy go to the shop and ask the shopkeeper whether he can clean her silver jewellery.)
Shopkeeper: Of course, I can polish them. Your silver jewelry will be like the first day.
Sindy: How do you do that?
Shopkeeper: Do you want to see how I do it?
Sindy: Yes, I would like to see.
Shopkeeper: If you want to come to my side, you can see how I do it.
Sindy: OK.
(The shopkeeper put the silver pieces in a container covered with aluminum foil and poured hot sodium liquid containing sodium bicarbonate on them. After leaving the silver items in the liquid for a while, he takes out them from the container and shows them to Sindy.)
Sindy: Yippee! They shine very well. Thank you.
Shopkeeper: But after a while, the brightness of them goes again and they get dark again. When it does happen again, come back here. I will polish them again.
Sindy: OK.
(Sindy and Brenda leave the shop and walk to their homes.)
Sindy: Actually, maybe we can polish silver items in our homes.
Brenda: How can we do it?
Sindy: Let's search!
– First, students form pre-defined groups.
– Second, the case material including text and questions are distributed to the groups.
– Third, the case representing a dialog among three persons is potrayed by three students. These students will read the text aloud to the whole class.
– Fourth, students are asked to write their answers on the paper by discussing the questions at the end of the text in groups.
– Finally, the answers given by all the groups to the questions are then taken one by one in turn and then discussed as a class. The following information will guide you through the discussion.
• In the first question, give five minutes for group discussion to argue how silver is tarnished, which chemical reaction occurs, and what the reducing and oxidizing agents are. Students may think that silver reacts with oxygen. But oxidation of silver is very difficult. If there are students who think so, ask them whether it is easy to oxidize silver. Once students think about it for a while, you can tell them that silver is very easily affected by sulfur in the weather, so it is tarnished. You can share the following information with your students.
Silver is tarnished under the influence of airborne sulfur, hydrogen sulfide (H2S) and sulfur dioxide gases, or when it is contacted with a sulfur-rich substance (egg yolk, sulfur rubber). The gases emitted from the exhaust gases of cars, fumes coming out from stones, and even the natural gas including sulfur affect the silver. Ask your students to write the reaction on their papers. (During the group work, you can give your students the clue that silver is tarnished because of the sulfur in the air environment. You can also give reactants and ask them to write the reaction).
Ag(s) + O2(g) + H2S(g) → Ask the groups, what kind of substances will form.
Unbalanced reaction: Ag(s) + O2(g) + H2S(g) → Ag2S(s) + H2O(g) |
Then ask your students to balance the reaction.
Balanced reaction: 4Ag(s) + O2(g) + 2H2S(g) → 2Ag2S(s) + 2H2O(g) |
Ask your students what is reduced and oxidized. (Silver (Ag) is oxidized, oxygen is reduced.)
Ask students to write half reactions on their paper. Then, ask a student to write half reactions on the board.
Oxidation half-reaction: 2Ag → 2Ag+ + 2e− |
Reduction half-reaction: O2 + 4e− → 2O2− |
• Regarding the second question, each group will be provided with the necessary equipment and they will try to clean a tarnished silver material by employing the process explained in the case.
Each group will carry out a cleaning experiment as indicated in the case. Before, the experiment, ask your students how to get the sodium bicarbonate solution needed for the experiment. Which substance we use in daily life includes sodium bicarbonate? (Answer: dough baking powder).
A silver material that has lost its brightness is thrown into hot sodium bicarbonate solution (dough baking powder) and left for a while. The silver material is then removed from the solution, washed with water (due to the sodium bicarbonate salt on it), then dried and displayed to the students. (The silver material is expected to be brighter than the old one).
• For the third question, each group is asked to explain the chemical process underlying the cleaning of tarnished silver materials, to write a balanced chemical reaction equation, and to identify reducing and oxidizing agents in the reaction. Each group first will write their answers on the paper. After finishing their answers, one of the students will write his/her group's answers on the blackboard and explain the related chemical process. Then, the other groups will discuss the answer under the guidance of the teacher and explain their answers. When necessary, the teacher provided clues to help students answer the questions. Discussion will continue until the right balanced chemical reaction equation, oxidizing and reducing agents, and half reactions are decided.
Students can give the following answer. In this case, ask students whether this reaction is written correctly or not.
Ag2S(s) + Al(s) → Ag(s) + Al2S3(aq) |
Ask students to balance the reaction.
Balanced reaction: 3Ag2S(s) + 2Al(s) → 6Ag(s) + Al2S3(aq) |
Also, ask students to balance the reaction by showing the electron exchange on their paper. Ask a student to do it on the board and then ask the class whether the student's work is correct or not.
Demonstrate how to balance the redox reaction with the class by using the half-reaction method.
The correct reaction is as follows (students may not write this equation):
Ag2S(s) + Al(s) → Ag(s) + Al3+(aq) + H2S(g) (basic medium) |
Say that the above reaction actually takes place during the cleaning process (by writing the actual reaction on the board). Then, ask students to balance the reaction with their groups.
Balanced reaction: 3Ag2S(s) + 2Al(s) + 6H2O(l) → 6Ag(s) + 2Al3+(aq) + H2S(g) + 6OH−(aq) |
Ask groups to show how they have balanced the reaction with the half-reaction method. Check the group work and guide them when necessary. By choosing a student from a random group, ask him/her to balance the reaction on the board by using the half-reaction method. If s/he was doing it wrong, ask another student to help him.
• Regarding the fourth and fifth questions, students will examine the cleaning process in terms of the materials used (i.e., sodium bicarbonate solution, hot water, and aluminum foil). Each group is asked what the functions of these materials are during the cleaning process. In addition, they are asked whether another material could be used instead of aluminum foil. After each group finished writing their answers, group answers will be shared with the class and discussed.
Sodium bicarbonate solution acts as an electrolyte. (Electrolyte definition can be given here). It provides the basic environment for the reaction. The warmth of the solution allows the reaction to take place faster, which allows the tarnished silver to be cleaned more quickly. (The students can be reminded of the effect of temperature on reaction rate.)
Because aluminum is a more active metal than silver, it separates silver from sulfide, and the aluminum ion in the aluminum foil reduces the silver ion (Ag+) in Ag2S to metallic silver.
We can use a metal that is more active than silver. The more active it is, the easier it will be to separate from the sulfide. (If necessary, students can be informed about activity, and reminded of previous information).
• Finally, each group will try to answer the sixth question. Regarding this question, each group will express their ideas about why copper materials turn green over time and which chemical reaction causes this situation. The whole class discussion will continue until reaching a consensus under teacher guidance.
Pure copper in yellowish pink color turns reddish brown when it is oxidized due to oxygen in the air. Ask your students to write the oxidation reaction of copper, and the half-reaction equations and to identify reduced and oxidized species.
2Cu(s) + O2(g) → 2CuO(s) (Copper is oxidized, oxygen is reduced) |
As the copper metal continues to be in contact with air, the surface of the metal gradually becomes green. The copper oxide reacts with CO2 and SO2 in the air and forms copper carbonate (Cu2CO3(OH)2) or copper sulfate (Cu4SO4(OH)6). The formed layer, called copper rust or patina, protects the underlying metal from other chemical agents, even though it is a very thin layer.
Note: If copper oxide is exposed to hydrogen gas, it will gain its old brightness again. (This information is given to the students and they are asked to write the reaction, to determine the reduced and oxidized substances, and to show half reactions.)
Copper ions are reduced and hydrogen is oxidized.
CuO(s) + H2(g) → Cu(s) + H2O(g). |
Footnote |
† This study is a part of the first author's doctoral dissertation and was presented at the 2014 NARST Annual International Conference at the Wyndham Grand Pittsburgh, PA, USA on March 30–April 2, 2014. |
This journal is © The Royal Society of Chemistry 2017 |