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Abstract | Cited by

An efficient and versatile Pd-catalyzed tandem C–N bond formation between aryl halides and primary amines is developed. The transformation allows a one-pot synthesis of phenoxazine and phenothiazine derivatives with a broad range of substitution patterns from readily available precursors.

Graphical abstract: Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines

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