Issue 21, 2017
From the journal:

Chemical Communications

End-to-end azido-pinned interlocking lanthanide squares†

Xiao-Lei Li,ab   Jianfeng Wu,a   Lang Zhao,a   Wei Shi, ORCID logo *b   Peng Cheng ORCID logo b  and  Jinkui Tang ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
E-mail: tang@ciac.ac.cn
Fax: +86 431 85262878

b Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), and Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China

Abstract

A rare end-to-end azido-pinned interlocking lanthanide square was self-assembled using a ditopic Schiff-base (H2L) and NaN3 as ligands. Obvious ferromagnetic interaction and a record anisotropy barrier of 152(4) K among lanthanide azido-bridged SMMs in a zero dc field were observed.

Graphical abstract: End-to-end azido-pinned interlocking lanthanide squares

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC00048K
Article type
Communication
Submitted
04 Jan 2017
Accepted
20 Feb 2017
First published
20 Feb 2017

Chem. Commun., 2017,53, 3026-3029

Permissions

Request permissions

End-to-end azido-pinned interlocking lanthanide squares

X. Li, J. Wu, L. Zhao, W. Shi, P. Cheng and J. Tang, Chem. Commun., 2017, 53, 3026 DOI: 10.1039/C7CC00048K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements