The traditional use of phosphorus compounds is as ligands for transition metals, however herein we synthesize Lewis acidic fluorophosphonium cation appended to a palladium complex and effect CO insertion into a Pd–C bond to obtain an unprecedented metal-benzoyl derived phosphorane.
K. F. Firth, J. Möbus and D. W. Stephan, Chem. Commun., 2016, 52, 13967 DOI: 10.1039/C6CC08561J
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