M.-M. Kima,
M.-H. Kimb,
S.-m. Ryub,
J. H. Lim*c and
D.-K. Choi*ab
aDepartment of Information Display Engineering, Hanyang University, Seoul 133-791, Korea. E-mail: duck@hanyang.ac.kr
bDepartment of Materials Science and Engineering, Hanyang University, Seoul 133-791, Korea
cDisplay R & D Center, Samsung Display Co., Ltd., Nongseo-dong, Kiheung-gu, Yongin, Gyeonggi-do 449-902, Korea. E-mail: lanosjh.lim@samsung.com
First published on 25th September 2015
We have developed a new technique to fabricate coplanar homojunction structure a-IGZO thin film transistors (TFTs) by adopting selective ultraviolet (UV) irradiation in the n+ source/drain regions of an a-IGZO layer through a patterned photoresist mask. In order to apply this technique for coplanar homojunction a-IGZO TFTs, we systematically studied the effect of dual wavelength (185 nm and 254 nm) UV irradiation time on the conductivity of a-IGZO films. Various materials were evaluated to find one that provided proper shielding against UV irradiation. The resistivity of the a-IGZO film drastically decreased from an as-deposited value of 2.71 × 106 Ω cm to 3.76 × 10−5 Ω cm after UV irradiation. The lowest resistivity obtained in this study is similar to that of ITO transparent electrodes and is about 2 orders of magnitude lower than the values obtained to date. Coplanar homojunction a-IGZO TFTs were successfully fabricated by introducing an optimized process that included UV irradiation through a patterned photoresist UV mask. The saturation mobility (μsat), threshold voltage (Vth), sub-threshold swing (SS), and on/off current ratio (Ion/Ioff) were measured to be 6.7 cm2 V−1 s, 7.3 V, 0.21 V per decade, and ∼109, respectively. Moreover, we showed that the UV irradiation technique provided both a low contact resistance due to the high conductivity in the source/drain region and a small channel length modulation due to non-thermal doping behavior. We believe that this UV irradiation process is a useful technique because it is simple and results in outstanding electrical properties.
In order to overcome this problem, many research groups have studied coplanar structured a-IGZO TFTs, which can minimize the overlap between the gate and the source/drain electrodes.5–8 Authors of these reports proposed the formation of an n+-doped a-IGZO film on the source/drain contact regions by selective exposure to Ar, He, and H2 plasma ambient.5,9,10 High conductivity can also be achieved by hydrogen diffusion into the a-IGZO film during plasma enhanced chemical vapor deposition (PECVD) of silicon nitride (SiNx) or silicon oxide (SiOx), which provide an etch stopper layer or a passivation layer.11 However, the n+ doping process using plasma treatment is rather complicated, and channel region may become narrow because hydrogen diffuses to channel region during the process due to high diffusivity.10 The effect of UV irradiation on the conductivity of a-IGZO films was investigated in a previous report. In that report, a-IGZO TFTs with a dual active layer were fabricated by inserting an embedded conductive layer using photo-chemical doping of the a-IGZO film by UV irradiation. The photo-chemical n+-doped a-IGZO channel showed an increase in carrier concentration of ∼1018 cm−3 from the background level of 1016 cm−3, and the overall characteristics of the TFT were improved as well.12
In this study, we investigated the effect of UV irradiation time on the resistivity of a-IGZO films and evaluated shielding materials for selective doping in the a-IGZO active layer. Then, we optimized a simple photo-chemical doping technique to fabricate coplanar homojunction a-IGZO TFTs. In addition to the superior electrical characteristics of a-IGZO TFTs fabricated using the UV irradiation process, we also demonstrated the advantage of the selective UV irradiation method over the other methods by estimating the contact resistance (Rsd) and channel length modulation (ΔL) using a transmission line method (TLM).
Many research groups have introduced various plasma treatment techniques and diffusion of hydrogen or fluorine into a-IGZO film using a PECVD process to decrease the resistivity.6,10,13,14 As shown in Table 1, the resistivity obtained by UV irradiation is significantly lower than those achieved for plasma-based n+ a-IGZO formation techniques previously reported. In the plasma-related techniques, the resistivity of a-IGZO films was all in the range of 10−3 Ω cm. The resistivities obtained from direct plasma treatment with Ar,9 H2,10 and He5 were 2.93 × 10−3 Ω cm, 4.8 × 10−3 Ω cm and 2.79 × 10−3 Ω cm, respectively, while the resistivity obtained from hydrogen diffusion during SiNx11 deposition by PECVD process was 6.20 × 10−3 Ω cm. Previous investigators have claimed that plasma treatment with H2, He, or Ar creates oxygen vacancies via bond breaking between metal and oxygen in a-IGZO.7,9,10,16
In our previous study, we fabricated a-IGZO TFT with high mobility by “permanent photo-chemical doping” via UV irradiation. The UV irradiation is known to break metal-oxide bonds and generate the charged oxygen vacancy such as Vo+ and Vo2+ from Vo neutral vacancy in oxide semiconductor. These phenomenon provide free electrons in oxide semiconductor, which leads to increase of carrier concentration.12,17 This UV irradiation technique is attractive because it is performed at room temperature in air ambient using commercially available UV cleaning equipment. Moreover, the line-of-sight nature of the UV exposure is advantageous for fabrication of coplanar homojunction TFTs that require accurate dimensional control.
In contrast, the definition of the n+ region during fabrication of coplanar TFTs is not easy in some of the plasma treatment techniques due to the diffusion of the chemical species.
A proper masking material is required in order to define the source/drain region in a coplanar homojunction TFT. We evaluated candidate masking materials including SiOx, AlOx and negative and positive photoresist (i.e., NPR and PPR, respectively). The thicknesses were 100 nm, 100 nm and 1.8 μm, respectively, which were chosen based on the typical values used in conventional TFT fabrication processes. After the UV shielding layer was deposited onto the a-IGZO layer, the sample was exposed to UV light for 3 h, which was followed by measurement of the resulting resistivity (Fig. 3). The 100 nm thick SiOx stacked a-IGZO film showed a resistivity of 1.41 × 10−4 Ω cm after UV exposure; this resistivity is almost the same as that of unshielded a-IGZO after UV irradiation (3.76 × 10−5 Ω cm). The resistivity was measured to be 1.63 × 10−1 Ω cm for the AlOx layer after UV exposure. Even though this value is about three orders of magnitude higher than that of the SiOx stacked a-IGZO film, the AlOx layer is still transparent to UV irradiation. Interestingly, the resistivities of PPR and NPR stacked a-IGZO films turned out to be 5.62 × 105 Ω cm and 4.09 × 105 Ω cm, respectively, after UV exposure. These values are close to the resistivity of the as-deposited a-IGZO film (2.71 × 106 Ω cm). Therefore, a simple process of selective UV irradiation through a patterned PR shielding layer can be effective in the fabrication of coplanar homojunction a-IGZO TFTs.
Fig. 4 shows the transfer characteristics of the a-IGZO TFTs without and with n+-doped a-IGZO source/drain (S/D) regions formed by UV irradiation for 3 h. All the processes were carried out identically for these two samples except for the selective UV irradiation of the source/drain areas. Several important parameters of the a-IGZO TFT such as saturation mobility (μsat), threshold voltage (Vth), subthreshold swing (SS) and on/off current ratio were compared at room temperature (298 K). The non-UV treated a-IGZO TFT exhibited a μsat of 0.6 cm2 V−1 s, Vth of 15.0 V, SS value of 0.90 V per decade, and on/off current ratio of ∼108. These inferior electrical properties were mainly attributed to the high contact resistance between the S/D and the active layer in the a-IGZO TFT.
On the other hand, the a-IGZO TFT with an a-IGZO S/D region n+-doped by UV irradiation showed enhanced electrical properties; specifically, the μsat, Vth, SS, and on/off current ratio were 6.7 cm2 V−1 s, 7.3 V, 0.21 V per decade, and ∼109, respectively. There was a 10 fold increase in the saturation mobility upon UV exposure. These data confirmed that the UV irradiation of the source/drain regions effectively reduced the contact resistance in the a-IGZO TFT. The inset in Fig. 4 provides the output characteristics of the a-IGZO TFT, which shows clear linear regions and no current crowding. The n+-doped a-IGZO TFT also showed a low contact resistance.18
To extract the contact resistance of the a-IGZO TFT, we measured the total resistance (RTOT) variation as a function of channel length in the range from 10 μm to 80 μm at a fixed channel width of 160 μm. The applied gate voltage (Vgs) was varied from 15 to 20 V at the drain voltage (Vd) of 0.1 V (Fig. 5). The a-IGZO TFT was operated in enhancement mode (Vth > 0 V), and all the channels were turned on for an accurate measurement of the resistance. The contact resistance of the source/drain (Rsd) and the channel length modulation (ΔL) were extracted by using the transmission line method (TLM). When Vds ≪ Vgs − Vth, the total resistance can be expressed by eqn (1):10,15,19
![]() | (1) |
RsdW is a suitable way to compare contact resistance with various n+ doping methods because it is independent of the TFT channel width and length. The estimated ΔL and RsdW values in our samples and other previously reported results are listed in Table 2 for comparison. In comparison with the plasma treatment methods or the hydrogen diffusion technique, the UV irradiation method shows both a very small ΔL and a low value of RsdW. This comparison demonstrates that the UV irradiation method provides precise doping control in the source/drain regions in coplanar homojunction a-IGZO TFTs with n+-doped a-IGZO. Based on these data, we believe that UV irradiation is a very useful and cost-effective way to fabricate a-IGZO TFTs with coplanar homojuction.
A suitable masking material for UV shielding must be chosen in order to employ the UV irradiation technique to fabricate coplanar homojunction TFTs. Among a number of shielding materials including AlOx, SiOx, and negative or positive photo-resist, the photo-resist layer turned out to be the most effective in masking UV light. Utilizing an optimized UV irradiation time and a patterned PR mask, we successfully fabricated coplanar homojunction a-IGZO TFTs. The a-IGZO TFT exhibited good electrical properties. The saturation mobility (μsat), threshold voltage (Vth), subthreshold swing (S/S), and Ion/Ioff ratio were 6.7 cm2 V−1 s, 7.3 V, 0.21 V per decade, and ∼109, respectively. In addition, the channel length modulation, ΔL, was calculated to be 0.4 μm, which is much smaller than the ΔL values obtained using the other doping techniques. The excellent performance of the a-IGZO TFTs was attributed to the nature of UV irradiation, which does not involve significant lateral diffusion. Consequently, we believe that the application of UV irradiation through a patterned PR mask can be a useful technique to enhance the performance of coplanar a-IGZO TFTs for high-resolution displays.
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