Issue 9, 2015

Optical and electrochemical properties of covalent assembled bis(4′-carboxylic phenyl terpyridyl) Ru(ii)-monolayer

Abstract

Homoleptic monomolecular layers of optically-rich and redox-active Ru(II)-4′carboxylic-phenyl-2,2′:6′,2′′-terpyridyl (1) have been fabricated on SiOx-based substrates. The optical and redox properties of the films have been studied in detail. The molecular films showed high electrochemical and thermal stability. The combination of thermal and electrochemical stability of the surface-confined assemblies could be useful for potential applications in materials science.

Graphical abstract: Optical and electrochemical properties of covalent assembled bis(4′-carboxylic phenyl terpyridyl) Ru(ii)-monolayer

Supplementary files

Article information

Article type
Paper
Submitted
04 Jun 2015
Accepted
16 Jul 2015
First published
16 Jul 2015

New J. Chem., 2015,39, 7403-7408

Author version available

Optical and electrochemical properties of covalent assembled bis(4′-carboxylic phenyl terpyridyl) Ru(II)-monolayer

P. C. Mondal, New J. Chem., 2015, 39, 7403 DOI: 10.1039/C5NJ01421B

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