Self-assembled crystalline nanostructures with sheaf-like morphology fabricated from tetra(4-aminophenyl)porphyrin and tetra(4-sulfonatophenyl)porphyrin are reported for the first time. The hierarchical sheaf-like growth of the assemblies exhibits Arrhenius behaviour. The observed morphology results from crystal splitting during initial oriented attachment growth followed by Ostwald ripening.
J. R. Eskelsen, K. J. Phillips, K. W. Hipps and U. Mazur, Chem. Commun., 2015, 51, 2663 DOI: 10.1039/C4CC09288K
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