James M.
Nyachwaya
*a,
Abdi-Rizak M.
Warfa
b,
Gillian H.
Roehrig
c and
Jamie L.
Schneider
d
aDepartment of Chemistry and Biochemistry and School of Education, North Dakota State University, 155B EML Hall, PO Box 6050, Fargo, ND 58108-6050, USA. E-mail: James.nyachwaya@ndsu.edu; Tel: +1-701-231-8538
bMetropolitan State University, 700 East 7th Street, St. Paul, MN 55106. E-mail: AbdiRizak.Warfa@metrostate.edu
cScience Education, 320 Learning and Environmental Sciences, 1954 Buford Ave., St. Paul, MN 55108, USA. E-mail: roehr013@umn.edu; Tel: +1-612-625-0561
dDepartment of Chemistry, University of Wisconsin - River Falls, 410 South 3rd Street, (CSH 215) River Falls, WI 54022, USA. E-mail: jamie.schneider@uwrf.edu; Tel: +1-715-425-3339
First published on 15th November 2013
This study sought to uncover memorized algorithms and procedures that students relied on in responding to questions based on the particulate nature of matter (PNM). We describe various memorized algorithms or processes used by students. In the study, students were asked to balance three equations of chemical reaction and then draw particulate representations of the compounds in the reactions. Students were then interviewed to uncover their understanding of underlying chemistry, taking note of any memorized algorithms that students were using. In addition to specific algorithms that students used, two trends were apparent from our analysis: (1) students successfully applied algorithms (in operations such as equation balancing) without necessarily understanding why they used the particular operations or processes. (2) Students have memorized processes and ideas which they incorrectly applied. Implications for assessment, research and instruction are also suggested.
In our past research (see Kern et al., 2010 and Nyachwaya et al., 2011), we uncovered gaps in students' conceptual understanding of the particulate nature of matter (PNM) related to chemical bonding. This research revealed a gap between students' understanding of chemistry at the symbolic level and their understanding at the particulate level (see Nyachwaya et al., 2011). While 99% of students in our study could correctly balance given equations of chemical reactions, only 30% drew appropriate particulate representations of the covalent compounds in these reactions. Ionic compounds were particularly problematic to represent at the particulate level, with less than 5% of students drawing appropriate particulate representations of the ionic compounds involved. The work presented in this paper is an extension of this previous study.
While our open-ended drawing tool elicits rich information about students' particulate knowledge of bonding, this paper and pencil assessment does not reveal student thinking in developing their particulate drawings. Thus, as a next step in our research, we conducted interviews to uncover students' conceptual understanding of underlying concepts represented in the different chemical equations. Specifically, we sought to understand students' thinking and reasoning processes during the equation balancing and drawing tasks. In this paper, we describe specific algorithms or memorized ideas and processes that students used related to the particulate nature of matter that were apparent from our interviews. We also describe the ways in which students used the algorithms or memorized processes.
Prior research has looked at the algorithmic learning in the context of problem solving, with a number of studies categorizing students into conceptual and algorithmic learners based on the types of problems they successfully solved (e.g.Sawrey, 1990; Nakhleh, 1993; Zoller et al., 1995; Zoller, 2000; Cartrette and Bodner, 2010). Our study was not conducted in the context of problem solving, nor did it involve quantitative problems. While confirming students' use of algorithms, this qualitative study documents algorithms students use, specifically related to PNM. We add to the existing knowledge in the field by reporting specific algorithms students used that relate to very fundamental aspects of PNM.
The overarching question guiding our work was:
What are college students' conceptual understandings of the particulate nature of matter (PNM)?
This specific paper was guided by the research question:
What specific algorithms and memorized processes do students use when responding to questions related to chemical reactions?
Another important construct for chemical understanding considers the different levels of representation necessary for complete, conceptual understanding. Chemistry is commonly represented at three levels: macroscopic, symbolic and submicroscopic or particulate levels (Johnstone, 1991). Students should understand chemistry at the three levels, recognize the level they are operating in, navigate between and within the levels fluently, and understand how the three levels contribute to understanding of chemical phenomena (Treagust et al., 2003). Explaining chemical phenomena requires the use of particulate and sometimes symbolic levels of representation (Treagust et al., 2003). This implies therefore that unless students understand the particulate nature of matter, they will not be able to make sense of and explain chemical phenomena (Dori and Hameiri, 2003). Unfortunately, research has shown that students struggle with representing chemistry at all three levels of representation, explaining chemistry at the three levels and the relationship between the levels (Yarroch, 1985; Bodner, 1991; Nakhleh, 1992, 1993; Bunce and Gabel, 2002; Treagust et al., 2003; Nyachwaya et al., 2011; Naah and Sanger, 2012).
Two types of learners have been identified, based on their learning approaches and success with different types of questions: algorithmic learners and conceptual learners. According to Pushkin (1998), “algorithmic learners can master assessment items requiring mimicking, regurgitation and short-term memorization, while conceptual learners can master assessment items requiring evaluation, comparison, and attribution skills” (p. 809). More recently, Grove and Bretz (2012), more recently suggested that students fall into four categories: (1) indifferent learners, (2) unaware learners, (3) transitional learners and (4) meaningful learners. This new scheme challenges the notion of a dichotomy that previously existed, instead placing learners on a continuum from rote memorization to meaningful learning. According to Grove and Bretz (2012), while indifferent learners resort to rote memorization, meaningful learners recognize a need to develop sound understanding of concepts and meaningful approaches to problem solving.
That students have been found to use formulas algorithmically without an understanding of the concepts underlying the problems (Bergquist and Heikkinen, 1990; Bodner, 2003), can be traced to some classroom practices and the way textbooks are written, where students are required to apply formulas without explaining what they are doing. Indeed, as Gabel (2003) warned, a lack of conceptual understanding by students leads them to carry out manipulations of mathematical equations which they have not thought about. For example, in a study involving college students, Zoller (2000), found that the students had a recipe they used to solve problems, where they applied memorized algorithms to solve problems, which they believed would always get them the ‘right answer’. The author concluded that, “students have been conditioned to think algorithmically” (p. 198).
Even when students have memorized algorithms, sometimes they may not apply them correctly. For example, in a study looking at high school students' quantum chemical concepts, Papaphotis and Tsaparlis (2008), found that students applied incorrect algorithms in arranging sub-shells in terms of energy demonstrating a lack of conditional knowledge-when to apply a specific algorithm (Nieswandt, 2007). In this study, the researchers found that student performance on questions requiring a combination of knowledge and critical thinking to be very low compared to those that required the application of algorithms. This finding agrees with others that have found students are more successful with tasks that can be solved with algorithmic processes (Nakhleh, 1993; Bodner, 2003).
The fact that some concepts and processes in chemistry are abstract and complex makes the subject challenging for many students. When students cannot understand these concepts and processes at a conceptual level, they resort to rote memorization (Stefani and Tsaparlis, 2009). Students revert to rote memorization when they cannot keep up with the pace of a course, and earn a good grade (Hammer, 1989). Students who memorize to get by on tests do not end up learning the intended material, or being able to use the memorized material to solve problems (Weissglass, 1993).
Assessments that emphasize or promote algorithmic learning have been associated with students' preference to memorize and attempt to use algorithms instead of aiming for conceptual understanding of underlying chemistry concepts (Zoller, 2002). In fact, some questions used in chemistry do not necessarily require any level of conceptual understanding. Instead, they require a mere recall of information or the application of algorithmic processes through specific steps or procedures for their solution (Zoller et al., 1995). Research has repeatedly shown that students use algorithmic strategies to solve problems, with no understanding of underlying concepts (Zoller et al., 1995, Nakhleh, 1993; Papaphotis and Tsaparlis, 2008). Contrary to conventional thought by teachers, students' ability to solve quantitative problems is not a satisfactory indicator for conceptual understanding, (Sawrey, 1990; Zoller et al., 1995). Assessments should require higher order cognitive skills (Zoller, 1993; Zoller et al., 1995; Tsaparlis and Zoller, 2003) and provide evidence for meaningful learning, which according to Novak (2002), occurs when tests do not exactly mirror what students saw during instruction. Teaching that only emphasizes solving problems without requiring demonstration of understanding of underlying concepts is not helpful especially in enabling students apply knowledge to novel situations (Dahsah and Coll, 2007).
Specific to chemical reactions, a number of studies have identified student struggles with the fundamental ideas and concepts that draw on chemical bonding and equations. Student struggles include confusion with subscripts and coefficients (Mulford and Robinson, 2002; Sanger, 2005), differentiating between atoms and molecules (Wood and Breyfogle, 2006), interpreting the information carried in chemical equations, such as the meaning of symbols (Wood and Breyfogle, 2006; Kern et al., 2010; Kelly et al., 2010). It has also been shown that while many students can balance equations of chemical reactions, they are for example unable to predict products of a reaction or draw appropriate particulate representations of the reactions (Davidowitz et al., 2010; Nyachwaya et al., 2011).
The instructor of the class is dedicated to students' conceptual understanding, explicitly addressing the particulate nature of matter throughout the course utilizing the three representations of chemistry, macroscopic, symbolic, and particulate. Active learning instructional strategies were used throughout the course, including interactive lectures with embedded clicker questions, offering think-pair-share opportunities for students, and the use of POGIL (Process-oriented Guided Inquiry Learning) activities, allowing students to explore and develop concepts.
Name | Year | Gender | Major | Semesters of HS chemistry |
---|---|---|---|---|
Note: all names used here are pseudonyms. | ||||
Mary | Freshman | F | Chemistry | Four |
Maggie | Freshman | F | Undecided | Two |
Julie | Freshman | F | Pre-med | Four |
Irene | Freshman | F | Biotechnology | Two |
Alex | Freshman | F | Biochemistry | Four |
Alexus | Sophomore | F | Food science | Two |
Frankline | Freshman | M | Conservation | Two |
Jayne | Senior | F | Biomedical sciences | Two |
Antonio | Freshman | F | Health/human performance | One |
Randy | Senior | M | Psychology | One |
Two forms of student data were collected: (1) students' written responses to each of the three open-ended drawing questions and (2) student interviews. Two of the open response questions were part of two different mid-term exams and the third open response item was part of the final course examination. The interviews took place a week before the course final examination. In this study, students were asked to balance three equations of chemical reactions and draw particulate level representations of the three reactions (Nyachwaya et al., 2011) (see Fig. 1). As the 10 participants completed these assessment items, they were asked semi-structured interview questions (Rubin and Rubin, 2005) to help us understand their thinking and decision making processes. Follow-up questions were asked to access students' reasoning for their drawing decisions. While many of the questions were generic, each student was asked questions specific to features of their drawings.
Question/equation | CH4 + O2 | AgNO3 + CaCl2 | HCl + CaCO3 |
---|---|---|---|
% correct balancing | 96 | 100 | 98 |
% appropriate particulate representation | 21.6 | 7.8 | 3.9 |
Question/equation | CH4 + O2 | AgNO3 + CaCl2 | HCl + CaCO3 |
---|---|---|---|
% correct balancing | 100 | 100 | 100 |
% appropriate particulate representation | 20 | 10 | 10 |
Of our 10 participants, only Randy and Franklin drew appropriate representations for reaction 1, while Antonio and Tanya drew appropriate particulate representations for reactions 2 and 3 respectively. None of the participants demonstrated particulate level understanding of the three reactions through their drawings. Tables 2 and 3 indicate student struggles with the particulate level of representation, confirming results from our earlier studies focused on covalent reactions (Kern et al., 2010 and Nyachwaya et al., 2011). This current study also indicates students' struggles with particulate representations of ionic reactions. It can also be seen from the tables that the 10 students who were interviewed are a representative of the class as a whole.
In the following sections, we identify and provide examples of how students used algorithms, instances where students successfully use memorized information without understanding the underlying chemistry, and cases of students misapplying memorized algorithms to answer questions. We found that the algorithms students used fell into two broad categories: symbolic level algorithms and particulate level algorithms. Our findings will be presented and discussed under these two broad categories.
The first thing I was taught to do back in high school is to start with the ‘C’ (referring to carbon in methane). Then I would look at the H's (meaning hydrogen) next, and then I would go to oxygen. I was taught to do H's and O's last.
Asked why she followed that procedure, she responded:
I don't know. My high school chemistry teacher taught us that you do H's and O's last. That's how I was taught.
While this algorithm or memorized procedure worked, students did not understand the process they were using. Our goal is to highlight the fact that the participant followed an algorithm (which worked) without an understanding of why it worked. He reason for its use was simply that it was how she was taught. This student was successful in balancing the given equation. However, following a heuristic without understanding why it works can be problematic especially in novel situations, where some judgment is needed. Also, it is possible that this tendency encourages rote memorization as opposed to learning for conceptual understanding. Equation balancing is usually taught early on in chemistry, and compared to other topics is not to be considered a difficult idea. Starting to memorize sets a bad precedence, which can lead to problems with conceptual understanding if a student chooses to focus on memorizing facts.
Asked why this process of converting charges into subscripts worked, Maggie replied:
I really don't know the reason behind it but just it is something I know that when you have a charge here or when it is something like three plus, it goes down here, to the other to whatever element is here.
Despite the fact that she knew that ‘the process of charge transfer occurs’ Maggie could not identify the ‘two’ as a subscript, instead calling it a coefficient. It is clear that she has memorized a process, which is charge transfer in this case, without knowing what a subscript is.
Similarly, Alex explained the significance of the subscript ‘two’ in the formula of calcium nitrate, stating,
the two comes from calcium because calcium has a two-plus and nitrate has minus one charge”[…] when they combine, you have to make sure that they are balanced together so that like one of them is not as overwhelming the other. You switch the charges on them so that they can combine. So this entire thing (referring to nitrate) gets a two and calcium gets a minus one.
Alex first referred to the subscript two as a di-nitrogen, later calling it a coefficient before eventually correctly identifying it as a subscript. Like Maggie, Alex could describe the ‘switching processes without knowing the name given to the number ‘two’ and ‘minus one’ that she used in describing the switching process.
It is kind of when you learn about this, you are just sort of told that they switch partners, or they switch which ones pair with which, but I guess I don't really know why they would decide to switch you know but I know it will depend on the amount of energy that is present, like some reactions will require energy for the switch to happen, others will release energy, but I don't know why they switch partners to begin with.
The misapplication of this algorithm became clear when students were asked to write an equation for dissolving sodium chloride in water. For example, Antonio wrote the following equation:
When asked to explain her choice of products, she replied:
When you write the equation, sodium will combine with oxygen while chlorine will combine with hydrogen to form the products.
The choice to use the approach of ‘switching partners’ follows given Antonio's description or understanding of what happens in a chemical reaction. From the equation that she wrote, it is evident that Antonio applied the algorithm of ‘switching partners’ in predicting the products and ultimately writing the equation.
In (ii) and (iii) above, the participant describes the process of ‘switching’ as occurring to achieve a certain purpose- for example, in (ii) above, the students described switching occurring “so that one is not overwhelmed”. It is interesting that the student is anthropomorphizing the reaction and also using a teleological explanation – to avoid overwhelming one of the species and a decision or need to switch partners. According to Talanquer (2007), teleological explanations describe an event as occurring to achieve a certain purpose. For example, students think of reactions taking place in order for atoms to achieve full shells (Taber, 2002; Taber and Adbo, 2013). In the results reported here, the student assigns ‘human’ qualities to particulate species-where they ‘decide to switch’.
Similarly, Mary identified reaction 3 as an acid–base reaction, but was not sure whether calcium carbonate was a base. Her criterion for classifying reactions was based on identifying some compounds in the reaction. When asked to use these criteria, she identified reaction 2 as a ‘salt reaction’, and reaction 1 as “one that gives off a gas”.
Like Mary, when asked to classify the three reactions, Julie's response was
I think equation one is oxidation reduction… through the process of elimination I guess. I think they are all oxidation–reduction reactions. For equation 3, HCl is an acid but it is not an acid–base because there is no base in the reaction… when I think of a base, I look for an OH as has been emphasized to us. In an acid, hydrogen is generally present.
Franklin was very clear about his use of memorized rules, stating that
I just memorize like the rules like whether it is a single replacement or a double replacement, a combustion reaction I look for oxygen, and in acid carbonate reactions, they give a salt, water and carbon dioxide.
These memorized criteria became a source of confusion some students. For example, For example, when Antonio was asked to classify the three reactions, she responded,
This one (referring to equation 1) I would look at like how there is water produced and so I kind of wonder if it is an acid base reaction kind of thing… based on the fact that there is a water produced. For equation two I see that the products are switching who they are with as ionic equations that we have been dealing with. For equation 3, there is water produced, so automatically my mind goes to acid base.
Our participants' reliance on algorithms is apparent in their classification of the three reactions. Student struggles with classification of reactions has been previously documented (Stains and Talanquer, 2008). While the algorithms help most students correctly classify the reactions, they hide the lack of understanding of other aspects of chemical reactions, such as identifying the reactant that is a base in reaction three. When an aspect of a students' algorithm does not fit with the information given, such as the absence of a compound with an OH, the algorithm does not work.
When asked why she had drawn the carbon atom in methane larger than the hydrogen, Mary responded,
Carbon would be bigger than hydrogen because it is the central atom
While the correct trend is shown in the drawing, Mary does not exhibit an understanding of why her drawing is appropriate. This lack of understanding of relative atomic sizes can also be seen in how she drew the water molecule in Fig. 3 above, where the hydrogen atoms do not appear to be of the same size, and are larger than the oxygen atom.
Julie's particulate drawing of reaction 1 (see Fig. 4) also shows correct relative sizes for C and H atoms in methane. When asked to explain her decision about these relative sizes she responded,
because carbon has six electrons I believe while hydrogen has one, and so technically it will be six times larger than hydrogen”.
This participant has clearly portrayed the correct relative sizes of atoms in Fig. 4 without a clear knowledge or understanding of the correct reason for the trend as shown. While the number of electrons in an atom bears some relationship to the size of an atom, the idea of direct proportionality inferred here is inaccurate.
Prior research has indicated student struggles with atomic and ionic size (Coll and Treagust, 2003; Nyachwaya et al., 2011). With the data presented here, we see that students' depiction of size is informed by an algorithm as opposed to conceptual knowledge and understanding. It is possible that some of the drawings that we considered appropriate may not have necessarily been informed by a good understanding of the underlying principles.
Note that the water molecule has the correct relative atomic sizes and molecular geometry as drawn. However, her reason for the drawing was not based on the knowledge of either the molecular geometry or relative atomic sizes:
I just drew it as a mickey mouse I don't know why. I don't know it just makes sense to me. It just makes sense to draw the center one bigger and the side ones smaller
It seems that the student knows the ‘mickey mouse’ shape of a water molecule (when drawn). Some probing however revealed that the student has been driven by the ‘mickey mouse’ idea more than correct conceptions of molecular geometry. Past research has shown that students struggle with the concept of molecular geometry (Nyachwaya et al., 2011). In our work specifically, we considered drawings like the one in Fig. 5 above to be appropriate. The interview data however leads us to speculate that some students used algorithms instead of conceptual understanding in their drawings.
I: from your drawings, you have used the same model to represent all compounds. Earlier, you defined aqueous as meaning ‘dissolved in water’. Describe to me what happens when you dissolve common salt, sodium chloride in water.
Alex: the salt dissolves in the water and you can barely see the salt particles. The salt breaks apart to form ions (see Fig. 6)
I: given this idea, (referring to the step above) how would you represent aqueous silver nitrate and aqueous calcium nitrate in equation 2?
Alex: we'll have…. Silver will be two plus, everything else will be negative. For calcium nitrate, we'll have… (See Fig. 7)
A second participant, Randy, used the idea of ‘breaking apart’ during the interview to explain his particulate drawings. The following excerpt shows his choices and reasoning:
I: could you name one property of ionic compounds
Randy: they are easily broken apart into ions. They are found in most salts.
I: what happens to a salt like calcium chloride when it is dissolved in water?
Randy: the salt breaks apart
I: could you then draw here what happens to calcium chloride in equation 2 when it is dissolved in water?
Randy: yes. I believe it will be (see Fig. 8)
I: you mentioned that ionic compounds are easily broken apart into ions. Could you draw here the ions you would see in calcium carbonate?
Randy: yes. I believe it will be like this (see Fig. 9)
These drawings are guided by the broad idea of ‘breaking apart’ mentioned by the participants in the excerpts above. In both cases, while the algorithm of breaking apart worked for compounds such as CaCl2, it did not work for AgNO3 and CaCO3, compounds with polyatomic ions. In the two instances, the participants indiscriminately applied the rule (algorithm) of ionic compounds breaking into constituent ions. While the algorithm works for ionic compounds composed of monoatomic ions, it clearly fails when applied to polyatomic ions. The students failed to realize that polyatomic ions react as a single unit (Smith and Metz, 1996; Nyachwaya et al., 2011; Naah and Sanger, 2012). These drawings point to a lack of understanding of the nature of polyatomic ions and also an overly generalized application of the algorithm of ‘splitting’ of ionic compounds.
The transcript below shows the student's account of her drawings.
I: looking at reaction 2 here, in silver nitrate you have silver ions and nitrate ions. How come you did not indicate ions in silver chloride here?
Alexus: because they are kind of like there one group so there is no like positive or negative charge on them because they are like a group together.
I: why will they not have charges on them?
Alexus: because we were just told they are not supposed to have ions. The ions are stripped from each other, but they like trade in so they don't form separate positive and negative.
I: so that would be the same case for calcium carbonate here?
Alexus: yes, so there is no positive and negative charge since they are grouped together they are one group where they share electrons and this is particularly the case for solids. They trade their ions to not have a positive or negative ion.
In this case, the student consistently uses the ‘rule’ that in solid ionic compounds, there are no ions at the particulate level – she uses the rule in equation silver chloride and calcium carbonate. As seen in Fig. 10, the student clearly differentiated how she drew aqueous ionic compounds at the particulate level. In our past work, we found that our most of our students (up to 95%) used a covalent bonding model to represent ionic compounds at the particulate level (Nyachwaya et al., 2011). In our subsequent work, we found that students particularly struggled to represent solid ionic compounds. This interview data gives us a glimpse into why students particularly struggle to represent solid ionic compounds at the particulate level.
Two themes emerged from our data: (1) successful use of algorithms without conceptual knowledge of why the algorithm works and (2) inappropriate use of algorithms. In the first case, students successfully applied algorithms in responding to interview questions. As evident from our results, despite the fact that students could perform routines such as ‘equation balancing’ following certain procedures, some could not explain why it would be necessary to start by balancing certain elements first. Indeed, a good number of chemistry students solve problems without understanding the concepts underlying the problems (Nakhleh and Mitchell, 1993; Chei, 2001; Tsaparlis and Zoller, 2003; Papaphotis and Tsaparlis, 2008). As Nakhleh (1993), and Robinson (2003) note, algorithms seem helpful, but reliance on them can hinder meaningful learning and conceptual understanding.
Also evident from our data are instances where students apply the wrong algorithm, or incorrectly use algorithms in answering particular questions. It is known that even when students have memorized algorithms, they may not apply them correctly (Papaphotis and Tsaparlis, 2008). From our results, students who relied on the ‘switching partners’ heuristic in double replacement reactions predicted the wrong products for dissolution of sodium chloride in water. Naah and Sanger (2012) cited a similar finding in their research on student misconceptions of dissolving ionic compounds in water. We suggest that a student can be successful when problem solving with algorithmic approaches – under some circumstances. The caveat is that algorithms are models, with assumptions and limitations and thus do not work under all scenarios. The expert knows this and acts accordingly; the novice is more haphazard in their approach. Participants in our study also seem to be lacking ‘conditional knowledge’ (Nieswandt, 2007), which would help them discern when particular information is useful for solving a given problem.
In order to successfully solve a problem, one has to understand what the problem is asking, what one is provided with, underlying, requisite concepts (Gabel, 1986) and knowledge of how to apply the concepts in solving the problem. Our results indicate that students rely on some of the information, such as some features of given equations in responding to questions. For example, a student took products of the combustion reaction (CO2 and H2O) as evidence for an acid–base reaction. In order to successfully solve a problem, one has to understand what the problem is asking, what one is provided with, underlying, requisite concepts (Gabel, 1986) and knowledge of how to apply the concepts in solving the problem. If we are to think of these as conditions necessary for successful problem solving, one needs all or a combination of them. For example, students correctly classified chemical reactions using surface features, such as the presence of carbon dioxide gas and water, but could not identify and acid or base in the reaction. This particular finding, of relying on surface features to classify reactions was noted by Stains and Talanquer (2008) in a study looking at classification of chemical reactions.
Traditional forms of assessment in chemistry are algorithmic and tend to focus on students' ability to solve problems and get the ‘correct answer, with teachers equating success at solving quantitative problems to conceptual understanding (Bennett, 2008; Pappa and Tsaparlis, 2011). Many of the traditional forms of assessment tend to focus more on students' ability to recall definitions and facts, and apply known formulas and algorithms to solve problems, and less on conceptual understanding (Gabel, 2003). Quantitative problems in particular often have steps that students can memorize and blindly apply-they promote algorithmic learning, at the expense of conceptual understanding and development of higher order cognitive skills (Zoller, 2002).
Designing effective assessments that will uncover students' reliance on algorithms or a lack of understanding of underlying chemistry is a challenge. In our past work (Nyachwaya et al., 2011), we developed and used an open-ended drawing tool to uncover students' conceptual understanding of the particulate nature of matter. We used students' particulate drawings to make judgments on their conceptual understanding. Our results in the present study reveal that this may not necessarily be the case. The open ended drawing tool helped us uncover students understanding of at the symbolic and particulate levels. Hidden behind the demonstrated competency is the reliance on algorithms as demonstrated by the results reported here. In saying this, we acknowledge the challenges of conducting interviews as a way of assessing students.
One of the biggest challenges that a college instructor faces in relation to rote learning is that their students have experienced many years of instruction and evaluation where rote learning has been encouraged. This experience makes it difficult for students to change their learning practices (Novak, 2002). This is especially true if the rote memorization has worked for them in the past. It is evident from the data above that tasks that students are used to solving did not go the extent of asking ‘why’. The student who balances equations using a memorized and practiced procedure successfully did not know why, beyond the fact that that is how they were taught. The student who has predicted products of reactions using the process of ‘switching partners’ has probably seen that work, until they encountered a case like dissolving sodium chloride in water, where the algorithm of switching partners' does not work. Changes to traditional teaching approaches that promote rote learning have been slow at best (Novak, 2002).
While heuristics sometimes make teaching of some ideas easy, it is important to point out to students that they do not always work. For example, while ‘switching partners’ can be a useful heuristic in predicting products of reactions in double replacement reactions, it does not work for dissolving salts in water (Naah and Sanger, 2012). A good possible approach to expose students to shortcomings of heuristics is to provide students with situations where the particular heuristics do not work and explicitly discuss the conditional thinking that underlies the use of a heuristic or algorithm.
The results reported here point to situations where instruction can lead to unintended consequences. While the rationale for ‘balancing some elements first’ when learning to balance chemical equations takes care of fractional coefficients, some of our participants seem to have missed the reasoning behind the move. Also, while it is true that water and carbon dioxide gas are products of an acid–base reaction, the two products are not necessarily an indication of an acid base reaction. With our results, instructors can anticipate algorithms that students are likely to pick up during instruction, especially during topics or concepts related to PNM and address them as appropriate. In the case where students are using teleological explanations, which are promoted by text books, while the intention is to help develop conceptual understanding (Taber and Watts, 1996), students will not necessarily take away the same message.
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