Issue 12, 2014
From the journal:

Dalton Transactions

Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2]− (M = Au, Ag)†

Sergio Sanz,a   Jamie M. Frost,a   Giulia Lorusso,b   Marco Evangelisti,b   Mateusz B. Pitak,c   Simon J. Coles,c   Gary S. Nichola  and  Euan K. Brechin*a  

* Corresponding authors

a EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131 650 6453
Tel: +44 (0)131 650 7545

b Instituto de Ciencia de Materiales de Aragon (ICMA), CSIC – Universidad de Zaragoza, Depto. Física Materia Condensada, 50009 Zaragoza, Spain

c UK National Crystallography Service, Chemistry, Faculty of Natural and Environmental Sciences, University of Southampton, Highfield Campus, Southampton, UK

Abstract

The linear [M(CN)2]− (M = Au, Ag) anions can be used as metalloligands in oxime-based Mn chemistry to afford 1D chains of [MnIII6] single-molecule magnets (SMMs).

Graphical abstract: Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2]− (M = Au, Ag)

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Article information

DOI
https://doi.org/10.1039/C3DT53502A
Article type
Communication
Submitted
13 Dec 2013
Accepted
23 Jan 2014
First published
23 Jan 2014

Dalton Trans., 2014,43, 4622-4625

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Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2]− (M = Au, Ag)

S. Sanz, J. M. Frost, G. Lorusso, M. Evangelisti, M. B. Pitak, S. J. Coles, G. S. Nichol and E. K. Brechin, Dalton Trans., 2014, 43, 4622 DOI: 10.1039/C3DT53502A

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