Issue 31, 2014
From the journal:

CrystEngComm

Ionothermal effects on low-dimensionality uranyl compounds using task specific ionic liquids†

P. A. Smitha  and  P. C. Burns*ab  

* Corresponding authors

a Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, IN 46556, USA
E-mail: pburns@nd.edu

b Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA

Abstract

Ionothermal methods were employed in the synthesis of two novel uranyl coordination compounds: [C5H6N]2 [UO2(C7H7SO3)4(H2O)] (1) and UO2(HAsO4)(NC5H11O2) (2), using pyridinium and betainium class ionic liquids. The results show novel ionic liquid incorporation and uranyl structural topologies, providing insight into the development of low-dimensionality uranyl complexes beyond traditional hydrothermal methods.

Graphical abstract: Ionothermal effects on low-dimensionality uranyl compounds using task specific ionic liquids

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Article information

DOI
https://doi.org/10.1039/C4CE00512K
Article type
Paper
Submitted
11 Mar 2014
Accepted
12 Jun 2014
First published
12 Jun 2014

CrystEngComm, 2014,16, 7244-7250

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Ionothermal effects on low-dimensionality uranyl compounds using task specific ionic liquids

P. A. Smith and P. C. Burns, CrystEngComm, 2014, 16, 7244 DOI: 10.1039/C4CE00512K

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