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Abstract | Cited by

A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

Graphical abstract: X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

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