Issue 40, 2013
From the journal:

RSC Advances

Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C–H bond twofold cleavage†

Juntae Mo,‡a   Sujin Lim,‡a   Sangjune Park,a   Taekyu Ryu,a   Sanghyuck Kima  and  Phil Ho Lee*a  

* Corresponding authors

a Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea
E-mail: phlee@kangwon.ac.kr
Fax: (+)-82-33-253-7582

Abstract

An efficient Rh-catalyed oxidative ortho-alkenylation is reported from the reaction of arylphosphine oxides with activated and non-activated alkenes as well. The developed method is characterized by high selectivity, a wide substrate scope, and an excellent functional group tolerance.

Graphical abstract: Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C–H bond twofold cleavage

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Article information

DOI
https://doi.org/10.1039/C3RA43764G
Article type
Communication
Submitted
27 Jun 2013
Accepted
26 Jul 2013
First published
31 Jul 2013

RSC Adv., 2013,3, 18296-18299

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Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C–H bond twofold cleavage

J. Mo, S. Lim, S. Park, T. Ryu, S. Kim and P. H. Lee, RSC Adv., 2013, 3, 18296 DOI: 10.1039/C3RA43764G

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