Issue 40, 2013
From the journal:

RSC Advances

Effect of ionic liquids on the conformation of a porphyrin-based viscometer†

Laramie P. Jameson,a   Joseph D. Kimball,b   Zygmunt Gryczynski,b   Milan Balaz*c  and  Sergei V. Dzyuba*a  

* Corresponding authors

a Department of Chemistry, Texas Christian University, Fort Worth, TX 76129, USA
E-mail: s.dzyuba@tcu.edu
Fax: +1 817 257 5851
Tel: +1 817 257 6218

b Department of Physics and Astronomy, Texas Christian University, Fort Worth, TX 76129, USA

c Department of Chemistry, University of Wyoming, Laramie, WY 82071, USA
E-mail: mbalaz@uwyo.edu
Fax: +1 307 766-2807
Tel: +1 307 766-4330

Abstract

Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.

Graphical abstract: Effect of ionic liquids on the conformation of a porphyrin-based viscometer

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Article information

DOI
https://doi.org/10.1039/C3RA43001D
Article type
Communication
Submitted
16 Jun 2013
Accepted
01 Aug 2013
First published
05 Aug 2013
This article is Open Access
Creative Commons BY license

RSC Adv., 2013,3, 18300-18304

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Effect of ionic liquids on the conformation of a porphyrin-based viscometer

L. P. Jameson, J. D. Kimball, Z. Gryczynski, M. Balaz and S. V. Dzyuba, RSC Adv., 2013, 3, 18300 DOI: 10.1039/C3RA43001D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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