Issue 5, 2013
From the journal:

CrystEngComm

Distinct interpenetrated metal–organic frameworks constructed from crown ether-based strut analogue†

Lei Liu,a   Xiaojun Wang,a   Quan Zhang,a   Qiaowei Li*b  and  Yanli Zhao*ac  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
E-mail: zhaoyanli@ntu.edu.sg

b Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, 220 Handan Road, Shanghai, China
E-mail: qwli@fudan.edu.cn

c School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Abstract

Rigid struts containing crown ether units (benzo-12-crown-4 and benzo-15-crown-5) coordinate with Zn4O(CO2)6 clusters, affording two different interpenetrated metal–organic frameworks (MOFs), i.e., benzo-12-crown-4-based MOF presents a “close contact” interpenetration mode, while the benzo-15-crown-5-based one has a “body center” interpenetration mode.

Graphical abstract: Distinct interpenetrated metal–organic frameworks constructed from crown ether-based strut analogue

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Article information

DOI
https://doi.org/10.1039/C2CE26401C
Article type
Communication
Submitted
30 Aug 2012
Accepted
19 Nov 2012
First published
19 Nov 2012

CrystEngComm, 2013,15, 841-844

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Distinct interpenetrated metal–organic frameworks constructed from crown ether-based strut analogue

L. Liu, X. Wang, Q. Zhang, Q. Li and Y. Zhao, CrystEngComm, 2013, 15, 841 DOI: 10.1039/C2CE26401C

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