Issue 2, 2013

A new topology constructed from an octamolybdate and metallomacrocycle coordination complex

Abstract

A novel complex, [CuI2L2]2[Mo8O26] (1), was hydrothermally synthesized by using ammonium molybdate, copper nitrate and 1,3-bis(imidazol-l-yl-methyl)benzene. Complex 1 exhibits a new 3D (3,4,6)-connected topological structure with a Schlafli symbol of (4·6·8)2(42·64·83·102·123)(44·62)2, which is constructed by [Mo8O26]4− anions linking a [4 + 4] metallomacrocycle.

Graphical abstract: A new topology constructed from an octamolybdate and metallomacrocycle coordination complex

Supplementary files

Article information

Article type
Communication
Submitted
04 Aug 2012
Accepted
27 Oct 2012
First published
29 Oct 2012

CrystEngComm, 2013,15, 249-251

A new topology constructed from an octamolybdate and metallomacrocycle coordination complex

G. Hou, X. Wang, Y. Yu, J. Gao, B. Wen and P. Yan, CrystEngComm, 2013, 15, 249 DOI: 10.1039/C2CE26250A

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