Martin
Oschatz
a,
Sören
Thieme
b,
Lars
Borchardt
a,
Martin R.
Lohe
a,
Tim
Biemelt
a,
Jan
Brückner
b,
Holger
Althues
b and
Stefan
Kaskel
*ab
aDepartment of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, D-01069 Dresden, Germany. E-mail: stefan.kaskel@chemie.tu-dresden.de; Fax: +49 351 46337287; Tel: +49 351 46333632
bFraunhofer Institute for Material and Beam Technology, Winterbergstraße 28, D-01277 Dresden, Germany
First published on 9th May 2013
A novel method for the preparation of highly mesoporous carbon materials (Kroll-Carbons; KCs) is described based on reactive carbochlorination etching of titania nanoparticles inside a dense carbon matrix leading to mesoporous carbons with precisely controllable porosity and high performance as cathode materials for lithium–sulphur (Li–S) batteries.
Especially in lithium–sulphur (Li–S) batteries,9 mesoporous carbons are ideal conductive host structures for embedding the active material. Sulphur-based cathodes exhibit a broad operating temperature10 as well as an intrinsic overcharge protection mechanism which greatly enhances the battery safety.11 Carbon materials, prepared by classical templating approaches, have been investigated for that purpose. CMK-3 with uniform and ordered mesopores showed promising reversible capacities12 and Liu and co-workers have optimized carbons with disordered mesopores for Li–S batteries.13 Ordered mesoporous carbons synthesized by a soft templating approach cause improved cycle life and performance at a high rate of 1 C.14 Mesoporous hollow carbon spheres15 as well as spherical OMC nanoparticles with bimodal mesoporosity prepared from polymeric opal structures16 were introduced as sulphur host for high rate Li–S batteries showing an excellent capacity.
In the following we present a new chemical method for the production of mesoporous carbon materials with very high internal pore volume of more than 3 cm3 g−1, specific surface areas ranging close to 2000 m2 g−1, and outstanding performance as cathodes in Li–S cells. They can be obtained by using high-temperature chlorination of titania in the presence of oxygen acceptors (also referred to as carbochlorination), which is the key step in the Kroll-process for the large-scale production of elemental titanium.17 In the following, such mesoporous carbon materials are named Kroll-Carbons (KCs).
For the production of KCs, titanium dioxide nanoparticles (Degussa P25, measured SSA: 50 m2 g−1) are mixed with sucrose as an inexpensive carbon precursor. The hydrocarbon undergoes an acid catalyzed polymerization, encapsulating the TiO2 nanoparticles, and is subsequently thermally converted into a carbon network under inert conditions. The titanium dioxide template is removed by dosing chlorine gas into the TiO2–carbon composite material according to the reaction TiO2 + 2 Cl2 + (2 + x) C → TiCl4 + 2 CO + x C, where the residual C represents the Kroll-Carbon (ESI,† Fig. S1). The useful by-product TiCl4 can be removed at the end of the reactor by distillation. KCs are of high purity (more than 99.5 wt% of carbon) as shown by electron dispersive X-ray spectroscopy (EDX) measurements. Thermal analyses under air atmosphere indicate complete carbon combustion, and powder XRD measurements of the KCs only show the characteristic graphite (002) peak at moderate intensity, indicating the absence of impurities as well as a certain degree of graphitization in the pore walls of KCs (Fig. S2, ESI†). They differ from carbide-derived carbons,18 which are produced by high-temperature chlorine treatment of carbides, since TiC formation is not observed before chlorine treatment at 900 °C (Fig. S2, ESI†).
Obtained KCs show remarkably high specific BET surface areas of 1989 m2 g−1 as shown by nitrogen physisorption measurements at −196 °C (Fig. 1, Table S1, and Fig. S3, ESI†). The resulting mesopores are uniform and highly accessible, resulting in a type IV isotherm with a distinctive H1 hysteresis loop. The over-all pore volume is as high as 3.1 cm3 g−1 due to the high amount of large mesopores making this new material suitable for the infiltration of large amounts of sulphur. The pore size distribution (PSD) calculated by using a QSDFT kernel (Fig. S4, ESI†) shows a multimodal distribution of pore diameters with maxima at 1 nm, 4.2 nm, and 18 nm. While the large pores originate from the titanium dioxide template particles, the smaller mesopores arise from empty spaces between the TiO2 nanoparticles due to incomplete filling of the template voids with precursor molecules during infiltration (Fig. S5, ESI†). Additionally, 0.3 cm3 g−1 micropores (1 nm in diameter) are generated by the CO evolution in the Kroll reaction in analogy to physical activation procedures. The carbon matrix surrounding the template particles serves as an oxygen acceptor in the Kroll process and its gasification is responsible for the significantly higher specific surface areas when compared to other mesoporous carbons prepared using wet chemical removal of SiO2 templates of similar size, which does not lead to the formation of micropores.13
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Fig. 1 Nitrogen physisorption isotherms (−196 °C) of KCs prepared from different TiO2 templates. |
Since the behavior and the performance of porous carbons in various applications strongly depends on the pore size, it is crucial for any synthetic route to allow control over the pore diameter as precisely as possible. In addition to Degussa P25, the KC synthesis was carried out with a series of template particles with higher specific surface areas corresponding to smaller particle size (Degussa P90, measured SSA: 100 m2 g−1 and in-house made TiO2 particles prepared by flame spray pyrolysis, measured SSA: 152 m2 g−1). The hysteresis loops in the nitrogen physisorption measurements shift towards lower relative pressures (Fig. 1) while the specific surface areas remain at the same level. The corresponding PSDs (Fig. S4, Table S1, ESI†) confirm the decreasing diameter of the large mesopores from 18 nm (Degussa P 25), to 11 nm (Degussa P 90), and 8.5 nm (in-house TiO2 particles), showing the possibility to precisely control the mesopore sizes of KCs. The total pore volumes decrease due to the lower pore diameters while the micropore sizes and -volumes stay at the same level.
SEM images of the KCs (Fig. S6, ESI†) show the presence of a distinctive arrangement of mesopores with block-shaped geometry and a foam-type structure which is responsible for the high internal pore volumes. The average sizes of the large mesopores in TEM images (Fig. 2a) is 15 to 25 nm and in good agreement with the nitrogen physisorption analysis. Moreover, the mesopore size is very close to the template dimensions (Fig. S7, ESI†) and the presence of some edges and corners of TiO2 nanoparticles confirm the carbochlorination reaction as being highly conformal (Fig. S8, ESI†). TEM images at higher magnifications (Fig. 2b) show the carbon microstructure of the KCs as an arrangement of mostly disordered sp2 carbon fringes.
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Fig. 2 TEM images of KCs prepared from Degussa P25 template particles. |
Kroll-Carbons from Degussa P25 templates offer a very high mesopore volume. They were infiltrated with different amounts of sulphur by melt infiltration, and the resulting composite structures were characterized with regard to their applicability as Li–S cathodes. In the following, the cathodes are denoted as KC/S_53, KC/S_60, KC/S_64 and KC/S_72 according to their sulphur content in wt% (Table S2, ESI†). Their surface is smooth but reveals a wide-open and highly accessible inter-particular porosity throughout the active material layer (Fig. S9, ESI†). The KC/S weight ratios determined by TGA are in good accordance with the expected values since the melt infiltration strategy allows precise control over the KC/S composite composition (Fig. S9, ESI†). The powder XRD patterns of KC/S composite cathodes (Fig. S10, ESI†) show that sulphur is completely melt-infiltrated and well dispersed inside the KC framework, effectively suppressing the crystal growth of sulphur particles due to the high amount of mesopores.12
The cycling stabilities of KC/S composite cathodes with variable sulphur content were characterized by galvanostatic cycling (Fig. 3 and Fig. S11, ESI†) at a constant rate of 167 mA g−1 (C/10). Please note that all capacity values are given in terms of mA h g−1 per sulphur mass, if not mentioned separately. High initial discharge capacities of 1089 mA h g−1 (KC/S_53), 1115 mA h g−1 (KC/S_60), 1046 mA h g−1 (KC/S_64), and 1038 mA h g−1 (KC/S_72) were determined for all cathodes. After a capacity decay of maximal 18% within the first 10 discharge–charge cycles, the KC/S composites exhibit an excellent cycling stability with highly consistent capacities of 806 mA h g−1 (KC/S_53), 820 mA h g−1 (KC/S_60), 817 mA h g−1 (KC/S_64), and 736 mA h g−1 (KC/S_72) after 80 cycles. For all composites, more than 70% of the initial discharge capacity can be reversibly utilized even at a very high sulphur loading of 72 wt% and at a low rate of C/10, although this is a combination which is known to cause extensive active material loss by lithium polysulfide shuttling and rupturing of the electrically conductive carbon backbone.19 The sulphur utilization is highly stable at approximately 50% and nearly independent of the amount of sulphur stored in the composite, since the 1 nm micropores and small 4.2 nm mesopores within the hollow KC walls are highly favorable for adsorption and contacting of sulphur species due to the high specific surface area. On the other hand, the high pore volume provided by the large 18 nm mesopores guarantees effective storage of nanometer-sized sulphur particles and fast lithium ion diffusion. KC/S_72 is most suitable for the application in energy storage systems since the initial discharge capacity of 747 mA h g−1 per cathode mass (including binder and conducting agent) is much higher compared to cathodes with lower sulphur content, making it both the more practical and cheaper choice since less host material is needed. Only a slight decrease in the cell discharge voltage is observed when the cathode is loaded with extraordinary high amounts of sulphur (72 wt%). This indicates that sufficient amounts of Li+ ions and electrons can diffuse to all reaction sites, facilitating the electrochemical conversion of sulphur at the large C/S interface area within Kroll-Carbon (Fig. S12, ESI†).
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Fig. 3 Cycling stabilities and coulombic efficiencies of the KC/S_64 (triangles) and KC/S_72 (squares) cathodes. |
A comparison of the electrochemical behavior of KCs with the well known mesoporous material CMK-3 (Fig. S13, ESI†) clearly shows the high potential of the new class of mesoporous carbons in Li–S cathodes (Fig. S14, ESI†). The CMK-3/S_53 and CMK-3/S_60 reference electrodes show significantly lower capacitance as compared to the KC/S_72 cathode at even lower sulphur loadings. Especially when the capacity related to the mass of the whole cathode is considered, the performance of Kroll-Carbon-based electrodes significantly exceeds that of CMK-3. This can be explained by the significantly higher pore volume and specific surface area of the KC leading to a rather complete utilization of encapsulated sulphur due to the large C/S interface and sufficient hollow space for electrolyte penetration and volume expansion. It should be mentioned that the electrochemical results of the ordered mesoporous reference material are in good accordance with the results presented by Nazar et al. and that a higher sulphur loading within this material is not achievable due to its limited porosity.
The KC/S_72 cathode laminated onto carbon-coated expanded aluminum current collector (CC) with about 3.0 mg (ED/Al) cm−2 exhibits a high active material: a CC weight ratio of 3.3:
1 leading to a very high capacity exceeding 450 mA h g−1 related to the cathode weight including the CC at C/10. Furthermore, very high current densities of 8.23 mA cm−2 (1 C) can be delivered when sacrificing a lot of the available capacity (feasible capacity: 110 to 160 mA h g−1 related to the electrode mass; Fig. S15, ESI†).
The Kroll-type reaction scheme using flame derived TiO2 nanoparticles as templates results in carbons with high specific surface area and pore volumes up to 1980 m2 g−1 and 3.1 cm3 g−1, respectively. The synthesis process is highly versatile for tailoring the pore morphology and diameter in a wide range. The novel materials prepared from a commercially available template material (Degussa P 25) show outstanding performance as sulphur host material in high capacity cathodes for lithium–sulphur batteries. Extremely high sulphur contents up to 72 wt% cause initial discharge capacities up to 747 mA h g−1 and stable cycling with reversible capacities of more than 550 mA h g−1 (related to the mass of the cathode).
Even though various mesoporous carbon materials show excellent performance as cathode materials in Li–S cells, all of them are derived by classical templating approaches and are thus difficult to produce on a larger scale. In our view, the Kroll-process, and especially the carbochlorination, is a valuable new process for upscaling the synthesis of mesoporous carbons with well-defined pore size. Even though chlorination at high temperatures is a dangerous and toxic process, the low price of chlorine and the possibility of reusing the by-product TiCl4 are highly attractive.
Financial support by the project “Nanomaterials for future generation Lithium Sulphur batteries” (“MaLiSu”) is gratefully acknowledged.
Footnote |
† Electronic supplementary information (ESI) available: Further material characterization; detailed electrochemical analysis and synthesis procedure of KCs. See DOI: 10.1039/c3cc42841a |
This journal is © The Royal Society of Chemistry 2013 |