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Abstract | Cited by

We report the synthesis and characterization of symmetric BODIPY dyads where the chromophores are attached at the meso position, using either a phenylene bridge or direct linkage. Both molecules undergo symmetry-breaking intramolecular charge transfer in the excited state, and the directly linked dyad serves as a visible-light-absorbing analogue of 9,9′-bianthryl.

Graphical abstract: Symmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyads

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