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Issue 2, 2012
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Enantioselective total synthesis of (−)-neovibsanin G and (−)-14-epi-neovibsanin G

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Abstract

The first total synthesis of vibsane-type diterpenoids neovibsanin G and 14-epi-neovibsanin G has been achieved. Key to this endeavour was a late stage EtAlCl2 mediated skeletal rich cascade leading to the bicyclo[3.3.1]nonane core in one step.

Graphical abstract: Enantioselective total synthesis of (−)-neovibsanin G and (−)-14-epi-neovibsanin G

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The article was received on 27 Sep 2011, accepted on 01 Nov 2011 and first published on 18 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC15995J
Citation: Chem. Commun., 2012,48, 287-289
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    Enantioselective total synthesis of (−)-neovibsanin G and (−)-14-epi-neovibsanin G

    J. Y. W. Mak and C. M. Williams, Chem. Commun., 2012, 48, 287
    DOI: 10.1039/C1CC15995J

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