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Abstract | Cited by

An Fe-based MOF has been constructed from a paddle-wheel-like dimeric Fe-cluster and a rod-shaped sinusoidal-like Fe-chain as two distinct secondary building units. Topological analyses indicate that this compound is a tetranodal (3,3,4,8)-connected net, which represents a new structural topology in MOFs. Moreover, the magnetic properties of 1 have been thoroughly investigated.

Graphical abstract: An Fe-based MOF constructed from paddle-wheel and rod-shaped SBUs involved in situ generated acetate

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