Issue 37, 2011
From the journal:

Chemical Communications

Selective oxidative debenzylation of mono- and oligosaccharides in the presence of azides†‡§

Mathäus Niemietz,a   Lukas Perkams,a   Joanna Hoffman,a   Steffen Ellera  and  Carlo Unverzagt*a  

* Corresponding authors

a Bioorganische Chemie, Gebäude NWI, Universität Bayreuth, 95440 Bayreuth, Germany
E-mail: carlo.unverzagt@uni-bayreuth.de
Fax: +49-921-555365
Tel: +49-921-552670

Abstract

When using benzyl ethers as permanent protecting groups in oligosaccharide synthesis selective oxidative debenzylation with NaBrO3 + Na2S2O4 under biphasic conditions is efficient and compatible with anomeric azides and many other functions.

Graphical abstract: Selective oxidative debenzylation of mono- and oligosaccharides in the presence of azides

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Article information

DOI
https://doi.org/10.1039/C1CC13884G
Article type
Communication
Submitted
29 Jun 2011
Accepted
29 Jul 2011
First published
18 Aug 2011

Chem. Commun., 2011,47, 10485-10487

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Selective oxidative debenzylation of mono- and oligosaccharides in the presence of azides

M. Niemietz, L. Perkams, J. Hoffman, S. Eller and C. Unverzagt, Chem. Commun., 2011, 47, 10485 DOI: 10.1039/C1CC13884G

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