Issue 17, 2011

Covalent ladder formation becomes kinetically trapped beyond four rungs

Abstract

Scrambling experiments suggest that the self-assembly of 2D ladders viaimine metathesis is kinetically trapped at four or more rungs. Consequently, ladders containing five or more rungs cannot be synthesized in high yield under the conditions used, as misaligned out-of-register byproducts cannot self-correct.

Graphical abstract: Covalent ladder formation becomes kinetically trapped beyond four rungs

Supplementary files

Article information

Article type
Communication
Submitted
02 Mar 2011
Accepted
16 Mar 2011
First published
28 Mar 2011

Chem. Commun., 2011,47, 5028-5030

Covalent ladder formation becomes kinetically trapped beyond four rungs

E. L. Elliott, C. S. Hartley and J. S. Moore, Chem. Commun., 2011, 47, 5028 DOI: 10.1039/C1CC11242B

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