Rainer
Ostermann
and
Bernd
Smarsly
*
University of Giessen, Institute of Physical Chemistry, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany. E-mail: bernd.smarsly@phys.chemie.uni-giessen.de; Tel: +00 49 641 99 34590
First published on 28th August 2009
Replacing the commonly used indium tin oxide (ITO) with a thin metal layer as a quasi-transparent electrode leads to enhancement and acceleration of the electrochromic response of WO3, as otherwise there is an electronic activation barrier at the interface between WO3 and the ITO electrode, impeding fast electron transfer.
WO3 is an ideal model system to study the influence of well-ordered mesoporosity (pores between 2 nm and 50 nm in size) on the electrochemical properties of nanoscale metal oxides, since the degree and speed of coloration/decoloration can be accurately measured and is directly related to the corresponding electrochemical processes. Recently, our group discovered that fully crystalline mesoporous WO3 films prepared by sol–gel templating exhibit good redox stability.5 It was expected that the presence of nanoscale porosity would substantially improve the coloration and decoloration by means of several effects: Firstly, a high surface area and thus a large interface between WO3 and the electrolyte can improve the diffusion of Li+ to and from WO3. Secondly, the ordered mesopore structure in turn partitions WO3 into small crystallites, thus decreasing the diffusion length inside the solid. Thus, the mesoporosity should facilitate Li+ insertion and desertion, but it was found that the coloration/decoloration kinetics were not substantially improved.5 Since the films were crack-free and showed excellent overall homogeneity, these results pointed to a further parameter governing the electrochromic response, namely the interface between tungsten oxide and transparent conducting oxides (TCOs) such as indium tin oxide (ITO) and fluorine-doped tin oxide (FTO).
For opto-electronic applications TCO materials like ITO or FTO are widely used as transparent electrode materials. Only recently, several studies showed that TCOs are not very suitable for organic photovoltaics6 due to a band mismatch which causes poor electron injection from p-type polymers to the ITO electrode. This behavior has been exploited in OLEDs (organic light-emitting diodes) by using a thin layer of wide-band-gap metal oxides like WO3 as a buffer layer thus increasing OLED efficiency. Measurements by Kelvin probe show that the work function increases from 4.7 eV (ITO) to 6.4 eV for WO3-covered ITO, in this case improving the hole injection from ITO–WO3 and limiting leakage currents.7,8
In the present study we have investigated the influence of TCO electrodes on the kinetics of Li+ insertion into WO3. It is shown that the interface between WO3 and TCO has a strong impact on the coloration kinetics, thus masking the effect of defined mesoporosity on Li+ insertion. As a potential alternative, it is demonstrated that the use of thin metal films instead of TCOs as transparent electrodes improves the electrochromic response of mesoporous or non-templated tungsten oxidethin films and demonstrates that defined mesopores indeed enhance these properties, especially with regard to kinetics.
For mesoporous WO3 layers, a dip-coating solution was prepared from 207 mg of the block copolymer H(CH2CH2CH2(CH)CH2CH3)89(OCH2CH2)79OH (referred to as ‘KLE’) dissolved in 6 mL of EtOH. To this solution 750 mg WCl6 dissolved in 4.5 mL EtOH and 3 mL THF was added and the resulting solution was stirred for 2 h. The solution was filtered with a 200 nm syringe filter and films were deposited on various substrates (Si wafers, ITO-coated glass slides, gold-coated glass slides). The relative humidity in the dip-coating chamber was adjusted to 5–10% and the withdrawal speed was 48 cm min−1. After dip-coating, the samples were kept at constant humidity for 2 min and then transferred into an oven at 80 °C. For further stabilization the samples were heated to 300 °C at a ramp of 5 °C and kept for 1 h at 300 °C. Thereby, the inorganic matrix was stabilized sufficiently without destroying the KLE template. Finally, the samples were calcined with a ramp of 5 °C min−1 to 550 °C, resulting in template removal and full crystallization of the inorganic matrix.
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Fig. 1 ΔOD for mesoporous WO3 films (thickness = 120 nm) on gold and ITO with electrode schematics. Inset (bottom right): 2D SAXS pattern in transmission mode for WO3 on metal with well-defined first-order maximum, i.e. mesoporosity. |
In fact, using a thin gold layer as a transparent electrode, the KLE-templated mesoporous WO3 films exhibit a pronounced enhancement of the electrochromic response compared to similarly prepared films on ITO-coated glass (Fig. 1). In particular, ΔOD is markedly increased, although the thickness of about 120 nm and the mesostructure of the films deposited on gold and ITO are almost identical, as both WO3 films were deposited by dip-coating using the same solution. The thickness was measured by profilometry and the 2D SAXS pattern in transmission geometry, (measured by using ultrathin Si substrates, see inset Fig. 1), i.e. with an angle of incidence of 90° between the X-ray beam and the film. The 2D SAXS pattern exhibits a well-defined first-order maximum, independent of the substrate (ultrathin Si substrate with and without metal layer). Similar to our previous studies, the structure corresponds to a bcc arrangement of ellipsoidally distorted spherical mesopores. Thus, the mesostructure is identical to the mesoporous WO3 films prepared on ITO or Si wafers and structure effects can be excluded as the origin of the differences in ΔOD. Surprisingly, no temperature dependence is observed for mesoporous WO3 films deposited on gold, proving that the temperature factor for the corresponding films on ITO has to be attributed to an activation barrier for electronic transfer at the ITO–WO3 interface. This electronic barrier is apparently negligible at the Au–WO3 interface. Similar observations are made when other metals (Pd, Pt) are used as electrodes; gold was chosen because it possesses the highest transparency and a thermal stability suitable for calcining the film at 550 °C. Such a high temperature is required to remove the block copolymer template and to crystallize WO3. Replacing ITO with other TCO materials like antimony-doped tin oxide (ATO) or FTO, i.e. using ATO- or FTO-coated glass as the substrate, did not produce better performances. This result is consistent with the explanation presented before, since the work functions (ATO: 4.8 eV, FTO: 4.4 eV) are similar to that of ITO (4.3–4.7 eV, the work function of ITO is altered by the heat treatments due to a decrease in oxygen vacancies). By contrast, the work function of gold is 5.2 eV, closer to the 6.4 eV observed for W(VI)O3 and 5.3 eV for W(V)O3. To further investigate whether the better performance of mesoporous WO3 on gold is only due to the sol–gel preparation method and the mesoporosity, WO3 films were also thermally evaporated on ITO and gold, and calcined afterwards in air at 550 °C to fully crystallize tungsten oxide and to ensure comparability with the mesoporous films treated under these conditions. The thickness and morphology of thermally evaporated films depend only to a small extent on the substrate, and the thickness can therefore be finely tuned.
Closer inspection of the absorbance during the redox cycles reveals that the kinetics of the electrochromic response of thermally evaporated WO3 on ITO also vary significantly with temperature, as can be seen in Fig. 2. For convenience, we present only the evolution of the absorbance during redox cycles (±1 V vs. Ag), since the evolution of the charge inserted/extracted is very similar to this curve (see Fig. S1 of the ESI† ).
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Fig. 2 Variation of absorbance at 630 nm during redox cycles (±1 V vs. Ag in 1 M LiClO4 in propylenecarbonate) at different temperatures for thermally evaporated 50 nm WO3 films prepared on ITO-(blue) and Au-(red) coated glass. |
In the case of thermally evaporated WO3 deposited on ITO (blue curve) the amount of charge inserted at 20 °C and therefore the coloration (increase in absorbance) is low and only gradually achieved, whereas at higher temperatures both kinetics and overall coloration improve. Likewise the oxidation and bleaching process is even slower. Therefore the reduction at −1 V vs. Ag was carried out for 1 min to reach about 95% of the film's maximum coloration (after which the rate of charge insertion became very small). The oxidation/bleaching at +1 V vs. Ag took as long as 2 min at low temperatures, but was significantly accelerated at 70 °C.
In contrast to the poor performance of thermally evaporated WO3 on ITO, such WO3 films prepared on gold (red curve) basically exhibit no temperature dependence and very fast kinetics, especially for the bleaching which was completed in a few seconds. This allows very fast switching times for applications.
Obviously, the transparency of the gold-coated glass was lower (85% compared to 95%), thus the absorbance curve is shifted to higher values (as if a constant filter had been applied), yet the crucial difference in absorbance remains unchanged. It is also worth noting that for the thermally evaporated films the maximum difference in absorbance was about 0.29 (and therefore the maximum charge capacity was about 9 mC cm−2, i.e. a coloration efficiency of 31–33 cm2 C−1) independent of the electrode. However, for WO3 this value was only reached at 70 °C on ITO, but on gold at all temperatures. Moreover, on gold surfaces the kinetics are always very fast, whereas on ITO high temperatures were needed to accelerate the electrochromic response. The thickness of the films also influences the response: for a layer of up to 125 nm of WO3 the electrochromic response is still accelerated on gold, whereas the kinetics on thicker WO3 films increasingly resemble those on ITO (see 250 nm of WO3 Fig. S2 of the ESI† ). As only the electrode material (ITO or Au) was changed, the electrolyte and therefore the Li+ insertion seem to exert little influence on the process, while the electronic transfer via the electrode–WO3 interface appears to be the rate-limiting factor. A complete interpretation of these findings is rather difficult, yet a mismatch of the band structures of ITO and WO3 is evidently one of the key factors. In agreement with the observations from OLED studies7,8 electron injection from WO3 into ITO is not favorable and oxidation/bleaching in electrochromism also requires this electron transfer. On gold the barrier for electronic transfer to and from the film is much smaller, thus allowing fast and complete reduction and oxidation, while on ITO the equilibrium, i.e. full coloration, is only attained at high temperatures. This line of argument is corroborated by cyclic voltammetry. Fig. 3a shows an almost reversible redox couple of WO3 on gold, while the reduction and oxidation peaks are separated by about 1 V on ITO. This overpotential is possibly due to the band mismatch between WO3 and ITO. The reduction peak around −0.8 V vs. Ag is followed by the oxidation peak at −0.7 V for WO3 on gold, whereas on ITO the oxidation only takes place around +0.2 V vs. Ag. Moreover, the temperature dependence on ITO is clearly seen.
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Fig. 3 a) Cyclic voltammograms (vs. Ag in 1 M LiClO4 in propylenecarbonate, 20 mV s−1) of thermally evaporated WO3 films on ITO and Au at different temperatures. b) Work functions for electrode materials. |
A similar enhancement in kinetics was reported in other electrochromic systems like Ni(OH)2 on metallic Ni9 or mostly amorphous WO3 on ITO, but with a thin gold overlayer onto which additional potentials can be applied.10 Hence, while the effect seems to be most pronounced for crystalline WO3, further experiments are needed to test amorphous WO3 and other electrochromic systems and thereby elucidate the underlying mechanisms. Because of recent advances in novel transparent electrodes like ZnO–Ag–ZnO11 with similar transparency to ITO and better conductivities, an application in a multilayer system might be feasible. Indeed, ZnS–Ag–ZnS has already been investigated by Leftheriotis et al. showing the feasibility of replacing TCO electrodes in electrochromic systems.12–14 Unfortunately, no data on the kinetics and crystallinity of these ZnS–Ag–ZnS–WO3electrodes are provided, yet interestingly in the cyclic voltammogram the separation of oxidation and reduction peaks is reduced by 400–500 mV on ZnS–Ag–ZnS compared to a TCO electrode, in this case FTO.14
Based on the findings of this work it is evident that in previous studies, including our studies, the influence of mesoporosity on electro-optical properties was masked by the electronic activation barrier between the WO3 and the ITO electrode, impeding fast electron transfer. This effect obscured the advantages of mesoporous organization, such as high surface area and good accessibility of the film for the electrolyte, but also the well-defined pore walls with the maximum thickness of 10–15 nm which represents the maximum diffusion path of the Li+ ions. Thus, the preparation of mesoporous WO3 on thin metal layers allows the unmasked influence of mesoporosity and nanoscaled crystallinity on electrochromism to be addressed. For this purpose, three types of samples were compared: WO3 with ordered mesopores (‘meso-WO3’) was templated by evaporation-induced self-assembly using a block copolymer , yielding deformed spherical mesopores placed on a distorted bcc lattice, with a diameter of ca. 14 nm parallel to the plane and ca. 8 nm perpendicular to the substrate. The treatment at 550 °C resulted in a highly crystalline WO3 matrix. A second type of sol–gel template material, i.e. a weakly porous WO3 film (‘low meso-WO3’), was obtained by using only 1/10 of the template, with otherwise identical conditions. These two sol–gel derived films were compared with a thermally evaporated WO3 film (‘evap-WO3’).
Fig. 4 shows the time necessary before a portion of the total bleaching is obtained, thus being more instructive than just comparing the time for 50% bleaching. As can be seen in Fig. 4, sol–gel derived mesoporous WO3 (‘meso-WO3 on Au’) possess the fastest electrochromic response, compared to a less porous WO3 film (‘low meso-WO3 on Au’), and to thermally evaporated WO3 (‘evap-WO3’). In fact, completely dense WO3 films, i.e. attaining bulk density, can hardly be prepared by sol–gel processing (even in evaporated films the porosity is about 5–10 vol%). Thus the advantage of the ordered mesoporosity is rather the well-defined pore walls and crystallite sizes and not primarily the higher porosity. A significant improvement in the bleaching time is visible for films with ordered mesoporosity on gold electrodes, but it was completely masked on ITO electrodes. Sputtered films or other materials that can be prepared in dense films should show slower kinetics.
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Fig. 4 Bleaching time against portion of total bleaching (i.e. the difference between fully colored and bleached state) for different porosities of 100–120 nm WO3 on Au and ITO (for definitions see text). |
Footnote |
† Electronic supplementary information (ESI) available: Comparison of the variation of absorbance and charge inserted/extracted for WO3 films on gold and ITO. Electrochromic response of WO3 films of different thickness. See DOI: 10.1039/b9nr00091g |
This journal is © The Royal Society of Chemistry 2009 |