Issue 35, 2007

The oxadiazolyldiazenido(1−) ligand: a remarkably versatile platform for the synthesis of heteropolynuclear transition metal complexes§

Abstract

Cyclo-condensation of aroyl hydrazides with the cationic tungsten–dichlorodiazomethane complex [BrW(dppe)2(N2CCl2)]+ affords neutral oxadiazolyldiazenido(1−) complexes which react readily with a wide range of transition and non-transition metal species to afford a novel series of crystallographically-characterised heteropolynuclear complexes containing bridging oxadiazolyldiazenido(1−) ligands.

Graphical abstract: The oxadiazolyldiazenido(1−) ligand: a remarkably versatile platform for the synthesis of heteropolynuclear transition metal complexes

Supplementary files

Article information

Article type
Communication
Submitted
20 Jul 2007
Accepted
23 Jul 2007
First published
08 Aug 2007

Dalton Trans., 2007, 3864-3867

The oxadiazolyldiazenido(1−) ligand: a remarkably versatile platform for the synthesis of heteropolynuclear transition metal complexes

H. M. Colquhoun, Y. F. Chan, C. J. Cardin, M. G. B. Drew, Y. Gan, K. Abd El Kader and T. M. White, Dalton Trans., 2007, 3864 DOI: 10.1039/B711166P

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