Issue 35, 2007
From the journal:

Dalton Transactions

Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions†‡

Geng-Geng Luo,a   Li-Rong Lin,a   Rong-Bin Huang*a  and  Lan-Sun Zhengab  

* Corresponding authors

a Department of chemistry, Xiamen University, Xiamen, People's Republic of China
E-mail: rbhuang@xmu.edu.cn

b State key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, People's Republic of China

Abstract

[Ag(UO2)3 (OAc)9][Zn(H2O)4(CH3CH2OH)2] (1, OAc = CH3COO−) crystallized from an ethanol solution and its structure was determined by IR spectroscopy, elemental analysis, 1H NMR, 13C NMR and X-ray crystallography; it is composed of [Zn(H2O)4(CH3CH2OH)2]2+ cations and [Ag(UO2)3(OAc)9]2− anions in which triuranyl [(UO2)(OAc)3]3 clusters are linked by the Ag ion.

Graphical abstract: Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions

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Article information

DOI
https://doi.org/10.1039/B708799C
Article type
Communication
Submitted
11 Jun 2007
Accepted
01 Aug 2007
First published
10 Aug 2007

Dalton Trans., 2007, 3868-3870

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Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions

G. Luo, L. Lin, R. Huang and L. Zheng, Dalton Trans., 2007, 3868 DOI: 10.1039/B708799C

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