Issue 6, 2004
From the journal:

Mendeleev Communications

Resolution and racemization of nonbenzenoid atropenantiomers

Pavel V. Novikov,a   Oleg R. Malyshev,b   Konstantin A. Lyssenkoc  and  Remir G. Kostyanovskya  

a N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation, ul. Kosygina, 4, Moscow, Russian Federation

b N.D.Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation, Leninsky prospekt, 47, Moscow, Russian Federation

c A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation, ul. Vavilova, 28, Moscow, Russian Federation

Abstract

The three-step synthesis of adduct 3 has been reinvestigated; enantiomers 3a and 3b have been separated by enantioselective chromatography and the racemization barrier of 3a was determined as ΔG[supne] = 24.4 kcal mol–1 (16 °C).

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Article information

DOI
https://doi.org/10.1070/MC2004v014n06ABEH002049
Article type
Communication
Submitted
29 Sep 2004

Mendeleev Commun., 2004,14, 310-312

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Resolution and racemization of nonbenzenoid atropenantiomers

P. V. Novikov, O. R. Malyshev, K. A. Lyssenko and R. G. Kostyanovsky, Mendeleev Commun., 2004, 14, 310 DOI: 10.1070/MC2004v014n06ABEH002049

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