Issue 6, 2004
From the journal:

Mendeleev Communications

Stereochemisty of 3,3-disubstituted 2-methoxy-1,2-oxazolidines

Remir G. Kostyanovsky,a   Volker Schurig,b   Konstantin A. Lyssenko,c   Oliver Trapp,b   Gul'nara K. Kadorkina,a   Vasily R. Kostyanovskya  and  Boris B. Averkievc  

a N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation, ul. Kosygina, 4, Moscow, Russian Federation

b Institut fuer Organische Chemie, Eberhard Karls Universitaet Tuebingen, Tuebingen, Germany, Auf der Morgenstelle 18, Tuebingen, Germany

c A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation, ul. Vavilova, 28, Moscow, Russian Federation

Abstract

The conformations and anomeric effects for 1–3 in solution and for 3 in the solid state were investigated. The resolution of 1 by enantioselective gas chromatography was carried out and activation parameters of inversion in 1 were determined. The asymmetric transformation of the title compounds in an optically active solvent is discussed.

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Article information

DOI
https://doi.org/10.1070/MC2004v014n06ABEH002036
Article type
Communication
Submitted
15 Sep 2004

Mendeleev Commun., 2004,14, 306-309

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Stereochemisty of 3,3-disubstituted 2-methoxy-1,2-oxazolidines

R. G. Kostyanovsky, V. Schurig, K. A. Lyssenko, O. Trapp, G. K. Kadorkina, V. R. Kostyanovsky and B. B. Averkiev, Mendeleev Commun., 2004, 14, 306 DOI: 10.1070/MC2004v014n06ABEH002036

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