An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations
Abstract
An enantiomerically pure dinuclear triple-stranded titanium(IV) helicate is formed from a dicatechol diimine ligand with an (R,R)-1,2-diaminocyclohexane spacer and its stereochemical features are elucidated by experimental and theoretical methods.