A helix electronic theory shows that complex molecular chiralities can be generalized on the basis of their inherent helicities and effects in stereochemical control conventionally attributed to steric hindrance might instead have an electronic basis.
A helix theory for molecular chirality and chiral interaction
D. Zh. Wang, Mendeleev Commun., 2004, 14, 244 DOI: 10.1070/MC2004v014n06ABEH002051
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