A dramatical difference in the stereoselectivity of 1,1-dimethylallene allylboration with allyl(chloro)- and triallylboranes has been revealed and applied to the synthesis of isomeric 7-methylene-6,6-dimethyl- and 6-(1-methylethylidene)-3-borabicyclo[3.3.1]nonanes.
Regioselectivity of 1,1-dimethylallene allylboration: synthesis of isomeric 6- and 7-methylene-3-borabicyclo[3.3.1]nonanes
S. Yu. Erdyakov, M. E. Gurskii, A. V. Ignatenko and Y. N. Bubnov, Mendeleev Commun., 2004, 14, 242 DOI: 10.1070/MC2004v014n06ABEH002053
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