Issue 12, 2003
From the journal:

Organic & Biomolecular Chemistry

Polyhalogenated heterocyclic compounds. Macrocycles from perfluoro-4-isopropylpyridine†

Richard D. Chambers,*a   Philip R. Hoskin,a   Alan R. Kenwright,a   Ali Khalil,a   Paul Richmond,a   Graham Sandford,*a   Dmitrii S. Yufitab  and  Judith A. K. Howardab  

* Corresponding authors

a Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: r.d.chambers@durham.ac.uk, graham.sandford@durham.ac.uk

b Chemical Crystallography Unit, University of Durham, South Road, Durham, UK

Abstract

Perfluoro-4-isopropylpyridine was used as a building block for the two-step synthesis of a variety of macrocyclic systems bearing pyridine sub-units which were characterised by X-ray crystallography. Electrospray mass spectrometry revealed that complexation of either cations and, unusually, anions is possible depending on the structure of the macrocycle.

Graphical abstract: Polyhalogenated heterocyclic compounds. Macrocycles from perfluoro-4-isopropylpyridine

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Article information

DOI
https://doi.org/10.1039/B303443G
Article type
Paper
Submitted
26 Mar 2003
Accepted
01 May 2003
First published
15 May 2003

Org. Biomol. Chem., 2003,1, 2137-2147

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Polyhalogenated heterocyclic compounds. Macrocycles from perfluoro-4-isopropylpyridine

R. D. Chambers, P. R. Hoskin, A. R. Kenwright, A. Khalil, P. Richmond, G. Sandford, D. S. Yufit and J. A. K. Howard, Org. Biomol. Chem., 2003, 1, 2137 DOI: 10.1039/B303443G

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