Issue 23, 2003
From the journal:

Chemical Communications

Excellent enantio-selective enclathration of (2R,3S)-3-methyl-2-pentanol in channel-like cavity of 3-epideoxycholic acid, interpreted by the four-location model for chiral recognition

Kazuaki Kato,*a   Kazuaki Aburaya,a   Yasuhito Miyake,a   Kazuki Sada,†a   Norimitsu Tohnaia  and  Mikiji Miyata*a  

* Corresponding authors

a Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: katochan@molrec.mls.eng.osaka-u.ac.jp; miyata@mls.eng.osaka-u.ac.jp
Fax: +81-6-6879-7404
Tel: +81-6-6879-7406

Abstract

Pure (2R,3S)-3-methyl-2-pentanol is resolved from the racemates by a steroidal host; the interpretation of the recognition mechanism based on the crystal structure reveals that CH/O interaction between the host and guest plays a decisive role in enantio-selective enclathration of the small aliphatic secondary alcohol.

Graphical abstract: Excellent enantio-selective enclathration of (2R,3S)-3-methyl-2-pentanol in channel-like cavity of 3-epideoxycholic acid, interpreted by the four-location model for chiral recognition

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Article information

DOI
https://doi.org/10.1039/B309755B
Article type
Communication
Submitted
13 Aug 2003
Accepted
15 Oct 2003
First published
30 Oct 2003

Chem. Commun., 2003, 2872-2873

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Excellent enantio-selective enclathration of (2R,3S)-3-methyl-2-pentanol in channel-like cavity of 3-epideoxycholic acid, interpreted by the four-location model for chiral recognition

K. Kato, K. Aburaya, Y. Miyake, K. Sada, N. Tohnai and M. Miyata, Chem. Commun., 2003, 2872 DOI: 10.1039/B309755B

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