Issue 2, 2000
From the journal:

New Journal of Chemistry

Synthesis and structure of platinum(II) complexes with mixed Ph2PNHP(O)Ph2/[Ph2PNP(O)Ph2]− or Ph2PC6H4NH2/[Ph2PC6H4NH]− hybrid ligands: new M–P–N–H···N–P metallacycles

Martin B. Smith*a  and  Alexandra M. Z. Slawinb  

* Corresponding authors

a Department of Chemistry, Loughborough University, Loughborough, Leics., UK
E-mail: m.b.smith@lboro.ac.uk

b School of Chemistry, University of St. Andrews, St Andrews, Fife, UK

Abstract

Transmetallation of K[Ph2P(E)NP(E)Ph2] (E=S or Se) with cis-[PtCl2(HL)2] [HL=Ph2PNHP(O)Ph2-P] gave the mixed platinum(II) compounds [Pt{Ph2P(E)NP(E)Ph2-E,E′}L(HL)] containing one deprotonated [Ph2PNP(O)Ph2]− ligand; X-ray crystallography reveals an unusual pseudo six-membered Pt–P–N–H···N–P metalloring structure.

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Article information

DOI
https://doi.org/10.1039/A908282D
Article type
Letter
Submitted
15 Oct 1999
Accepted
09 Dec 1999
First published
07 Feb 2000

New J. Chem., 2000,24, 65-67

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Synthesis and structure of platinum(II) complexes with mixed Ph2PNHP(O)Ph2/[Ph2PNP(O)Ph2]− or Ph2PC6H4NH2/[Ph2PC6H4NH]− hybrid ligands: new M–P–N–H···N–P metallacycles

M. B. Smith and A. M. Z. Slawin, New J. Chem., 2000, 24, 65 DOI: 10.1039/A908282D

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