Issue 2, 2000
From the journal:

New Journal of Chemistry

Phosphino-urea chemistry: preparation and structure of chelate and P–N bond cleavage complexes

Alexandra M. Z. Slawin,a   Matthew Wainwrighta  and  J. Derek Woollins*a  

* Corresponding authors

a Department of Chemistry, University of St. Andrews, The Purdie Building, Fife, UK

Abstract

Reactions of Ph2PNRC(E)NRPPh2 proceed to give simple P,P chelate complexes when E=O but give the unexpected five-membered true heterocycle Pt[Ph2PN(Me)C(NMeH)S]Cl2 and an unusual six-membered Pd2P2O2 ring when E=S. The X-ray structures of three examples are reported.

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Article information

DOI
https://doi.org/10.1039/A908153D
Article type
Letter
Submitted
09 Oct 1999
Accepted
22 Nov 1999
First published
10 Mar 2000

New J. Chem., 2000,24, 69-71

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Phosphino-urea chemistry: preparation and structure of chelate and P–N bond cleavage complexes

A. M. Z. Slawin, M. Wainwright and J. Derek Woollins, New J. Chem., 2000, 24, 69 DOI: 10.1039/A908153D

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