Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh 4 (µ-PyS 2 ) 2 (cod) 4 ] n (H 2 PyS 2 = 2,6-dimercaptopyridine)

Miguel A. Casado; Jesús J. Pérez Torrente; Andrew J. Edwards; Luis A. Oro; Miguel A. Ciriano; Fernando J. Lahoz

doi:10.1039/B004750N

View PDF Version

DOI: 10.1039/B004750N (Paper) CrystEngComm, 2000, 2, 125-127

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh₄(µ-PyS₂)₂(cod)₄]_n (H₂PyS₂ = 2,6-dimercaptopyridine)

(Note: The full text of this document is currently only available in the PDF Version )

Miguel A. Casado, Jesús J. Pérez Torrente, Andrew J. Edwards, Luis A. Oro, Miguel A. Ciriano and Fernando J. Lahoz

Abstract

The reaction of the complex [Rh₄(µ-PyS₂)₂(cod)₄], containing two juxtaposed coordination donor sites, with CuCl creates the coordination polymer [ClCuRh₄(µ-PyS₂)₂(cod)₄]_n. This polymeric structure results from the self-assembly of alternating rhodium tetranuclear complexes and CuCl as linking units, and shows zigzag chains containing exclusively homochiral tetranuclear building blocks

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2 = 2,6-dimercaptopyridine)

(Note: The full text of this document is currently only available in the PDF Version )

Abstract

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh₄(µ-PyS₂)₂(cod)₄]_n (H₂PyS₂ = 2,6-dimercaptopyridine)