Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh 4 (µ-PyS 2 ) 2 (cod) 4 ] n (H 2 PyS 2 = 2,6-dimercaptopyridine)

Miguel A. Casado; Jesús J. Pérez Torrente; Andrew J. Edwards; Luis A. Oro; Miguel A. Ciriano; Fernando J. Lahoz

doi:10.1039/B004750N

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DOI: 10.1039/B004750N (Paper) CrystEngComm, 2000, 2, 125-127

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh₄(µ-PyS₂)₂(cod)₄]_n (H₂PyS₂ = 2,6-dimercaptopyridine)

(Note: The full text of this document is currently only available in the PDF Version )

Miguel A. Casado, Jesús J. Pérez Torrente, Andrew J. Edwards, Luis A. Oro, Miguel A. Ciriano and Fernando J. Lahoz

Abstract

The reaction of the complex [Rh₄(µ-PyS₂)₂(cod)₄], containing two juxtaposed coordination donor sites, with CuCl creates the coordination polymer [ClCuRh₄(µ-PyS₂)₂(cod)₄]_n. This polymeric structure results from the self-assembly of alternating rhodium tetranuclear complexes and CuCl as linking units, and shows zigzag chains containing exclusively homochiral tetranuclear building blocks

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Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2 = 2,6-dimercaptopyridine)

(Note: The full text of this document is currently only available in the PDF Version )

Abstract

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh₄(µ-PyS₂)₂(cod)₄]_n (H₂PyS₂ = 2,6-dimercaptopyridine)