Issue 23, 2000
From the journal:

CrystEngComm

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2 = 2,6-dimercaptopyridine)

Miguel A. Casado,   Jesús J. Pérez Torrente,   Andrew J. Edwards,   Luis A. Oro,   Miguel A. Ciriano  and  Fernando J. Lahoz  

Abstract

The reaction of the complex [Rh4(µ-PyS2)2(cod)4], containing two juxtaposed coordination donor sites, with CuCl creates the coordination polymer [ClCuRh4(µ-PyS2)2(cod)4]n. This polymeric structure results from the self-assembly of alternating rhodium tetranuclear complexes and CuCl as linking units, and shows zigzag chains containing exclusively homochiral tetranuclear building blocks

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Article information

DOI
https://doi.org/10.1039/B004750N
Article type
Paper

CrystEngComm, 2000,2, 125-127

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Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2 = 2,6-dimercaptopyridine)

M. A. Casado, J. J. Pérez Torrente, A. J. Edwards, L. A. Oro, M. A. Ciriano and F. J. Lahoz, CrystEngComm, 2000, 2, 125 DOI: 10.1039/B004750N

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