Issue 21, 2000
From the journal:

Chemical Communications

Zirconium complexes of a tacn-derived amido ligand and ring-opening to form a new diamido-amino pincer

Garth R. Giesbrecht,a   Alex Shafira  and  John Arnold*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, and the Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720-1460.
E-mail: arnold@socrates.berkeley.edu

Abstract

The tribenzyl complex (Pri2tacn)Zr(CH2Ph)3 eliminates toluene upon heating with concomitant ring-opening of the anionic ancillary macrocycle to yield [CH2[double bond, length half m-dash]CHNCH2- CH2N(Pri)CH2CH2NPri ]Zr(CH2Ph)2; the latter features a new class of dianionic pincer ligand.

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Article information

DOI
https://doi.org/10.1039/B005675H
Article type
Communication
Submitted
13 Jul 2000
Accepted
19 Sep 2000
First published
18 Oct 2000

Chem. Commun., 2000, 2135-2136

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Zirconium complexes of a tacn-derived amido ligand and ring-opening to form a new diamido-amino pincer

G. R. Giesbrecht, A. Shafir and J. Arnold, Chem. Commun., 2000, 2135 DOI: 10.1039/B005675H

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