Issue 21, 2000
From the journal:

Chemical Communications

Hydride transfer reactions in dimolybdenum compounds: a simple route to the novel μ-η1∶η1-tetrahydroboride complex [Mo2Cp2(μ-SMe)3(μ-BH4)]

Philippe Schollhammer,a   Nolwenn Cabon,a   François Y. Pétillon,*a   Jean Talarmina  and  Kenneth W. Muir*b  

* Corresponding authors

a UMR CNRS 6521, Chimie, Electrochimie Moléculaires et Chimie Analytique, Faculté des Sciences, Université de Bretagne Occidentale, BP 809, Brest-Cedex, France.
E-mail: francois.petillon@univ-brest.fr

b Chemistry Department, University of Glasgow, Glasgow, Scotland, UK

Abstract

The reaction of NaBH4 with the bis-nitrile compound [Mo2Cp2(μ-SMe)3(MeCN)2](BF 4) 1 unexpectedly gives rise to the rare, stable μ-(η1-H):(η1-H) tetrahydroborato complex [Mo2Cp2(μ-SMe)3(μ-BH4)] 2, in addition to the expected azavinylidene product [Mo2Cp2(μ-SMe)3(μ-η1 -NCHMe)] 3.

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Article information

DOI
https://doi.org/10.1039/B006457M
Article type
Communication
Submitted
07 Aug 2000
Accepted
27 Sep 2000
First published
18 Oct 2000

Chem. Commun., 2000, 2137-2138

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Hydride transfer reactions in dimolybdenum compounds: a simple route to the novel μ-η1∶η1-tetrahydroboride complex [Mo2Cp2(μ-SMe)3(μ-BH4)]

P. Schollhammer, N. Cabon, F. Y. Pétillon, J. Talarmin and K. W. Muir, Chem. Commun., 2000, 2137 DOI: 10.1039/B006457M

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