The reaction of nitrotriazolo[1,5-α]pyrimidines 1 with primary amines leads to cleavage of the pyrimidine ring, whereas triazole ring opening takes place in the reaction of 1 with secondary amines.
V. V. Voronin, E. N. Ulomsky, V. L. Rusinov and O. N. Chupakhin, Mendeleev Commun., 1999, 9, 200 DOI: 10.1070/MC1999v009n05ABEH001169
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