Ethane reacts with CO without solvent in the presence of polyhalomethane·2AlBr3 superelectrophilic systems to form EtCOOR after alcoholysis together with small amounts of corresponding esters of 1- and 2-bromopropanoic acids.
A. V. Orlinkov, I. S. Akhrem and S. V. Vitt, Mendeleev Commun., 1999, 9, 198 DOI: 10.1070/MC1999v009n05ABEH001163
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