Novel generation of silacarbonyl ylides by trapping of silylene with carbonyl compounds and their cycloaddition leading to silaheterocycles

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Norio Sakai, Tsuyoshi Fukushima, Satoshi Minakata, Ilhyong Ryu and Mitsuo Komatsu


Abstract

The photochemical generation of silacarbonyl ylides from a silylene and carbonyl compounds and their inter- or intra-molecular 1,3-dipolar cycloaddition with olefins leading to silicon heterocycles in one step was successful.


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