DOI: 10.1070/MC1998v008n03ABEH000920
(Paper)
Mendeleev Commun., 1998, 8, 95-96
An investigation of potassium µ-oxobis[pentachlororuthenium(IV)] in hydrochloric acid solution under microwave irradiation
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Alexander A. Nesterov , Alexander V. Bashilov , Valentin K. Runov and Nicolai M. Kuz'min
Abstract
A study of the ruthenium(IV) and (III) species in HCl solution under microwave irradiation shows a decrease in hydrolysis time, depolymerisation and reduction of ruthenium(IV) to ruthenium(III) by an order of magnitude, as compared with conventional heating of solutions in a boiling water bath.