Nickel-catalysed cross-coupling reactions of aryl halides with organostannanes

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Eiji Shirakawa, Kenji Yamasaki and Tamejiro Hiyama


Abstract

A triphenylphosphine–nickel complex is found to be an active catalyst for the cross-coupling reactions of various types of aryl halides, including unactivated aryl chlorides, with alkynyl-, alkenyl- and allyl-stannanes to give the corresponding coupled products in high yields.


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