View PDF Version
 
DOI: 10.1039/A703358C (Paper) Reference Section for: J. Chem. Soc., Faraday Trans., 1997, 93, 3939-3944

Radiolysis of aqueous solutions with pulsed helium ion beams Yield of (SCN)2-formed by scavenging OH as a function of SCN-concentration

(Note: The full text of this document is currently only available in the PDF Version )

Norihisa Chitose, Yosuke Katsumura, Zhihua Zuo, Masafumi Domae, Kenkichi Ishigure and Takeshi Murakami

Abstract

The concentration dependence of G[(SCN)2-] in the radiolysis of aqueous KSCN solutions with pulsed 24 MeV He2+ ions has been measured. The yield increased with increasing concentration below 0.1 mol dm-3, and in the measured concentration range the yield for 21 MeV He2+ was smaller than for an electron beam. The results have been compared with the reported GOH derived from various scavengers. The data did not agree at high scavenging capacity. It was suggested that the product yields do not equal GOH because part of the products disappear by intra-track reactions at high scavenging capacity particularly in high linear energy transfer (LET) radiolysis. It was confirmed qualitatively by the deterministic diffusion kinetic calculations.

References

  1. A. O. Allen, The Radiation Chemistry of Water and Aqueous Solutions, Van Nostrand Reinhold, Princeton, New Jersey, 1961 Search PubMed.
  2. I. G. Draganic and Z. D. Draganic, The Radiation Chemistry of Water, Academic Press, New York, 1971 Search PubMed.
  3. J. A. LaVerne, R. H. Schuler, A. B. Ross and W. P. Helman, Bibliography of Studies of the Heavy Particle Radiolysis of Liquids and Aqueous Solutions, NDRL Special Report SR-124, (revised) 1988 Search PubMed.
  4. W. G. Burns and H. E. Sims, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 2803 RSC.
  5. J. A. LaVerne, Radiat. Res., 1989, 118, 201 CAS and references therein.
  6. J. A. LaVerne and H. Yoshida, J. Phys. Chem., 1993, 97, 10720 CrossRef CAS.
  7. W. G. Burns, R. May, G. V. Buxton and G. S. Tough, Faraday Discuss., Chem. Soc., 1977, 63, 47 RSC.
  8. W. G. Burns, R. May, G. V. Buxton and G. S. Wilkinson-Tough, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 1543 RSC.
  9. S. A. Rice, V. J. Playford, W. G. Burns and G. V. Buxton, J. Phys. E.: Sci. Instrum., 1982, 15, 1240 Search PubMed.
  10. M. C. Sauer Jr, K. H. Schmidt, E. J. Hart, C. A. Naleway and C. D. Jonah, Radiat. Res., 1977, 70, 91 CAS.
  11. M. C. Sauer Jr, K. H. Schmidt, C. D. Jonah, C. A. Naleway and E. J. Hart, Radiat. Res., 1978, 75, 519.
  12. M. C. Sauer Jr, E. J. Hart, C. A. Naleway, C. D. Jonah and K. H. Schmidt, J. Phys. Chem., 1978, 82, 2246 CrossRef.
  13. M. C. Sauer Jr, C. D. Jonah, K. H. Schmidt and C. A. Naleway, Radiat. Res., 1983, 93, 40.
  14. G. E. Adams, J. W. Boag, J. Currant and B. D. Michael, in Pulse Radiolysis, ed. M. Ebert, J. P. Keene, A. J. Swallow and J. H. Baxendale, Academic Press, London, 1965, p. 117 Search PubMed.
  15. L. Dogliotti and E. Hayon, J. Phys. Chem., 1968, 72, 1800 CrossRef CAS.
  16. D. Behar, P. L. T. Bevan and G. Scholes, J. Phys. Chem., 1972, 76, 1537 CrossRef CAS.
  17. D. H. Ellison, G. A. Salmon and F. Wilkinson, Proc. R. Soc. London A, 1972, 328, 23 CAS.
  18. T. P. Zhestkova, A. K. Pikaev and V. N. Spitsyn, Dokl. Phys. Chem., Proc. Acad. Sci. USSR, 1972, 204, 482 Search PubMed.
  19. R. H. Schuler, L. K. Patterson and E. Janata, J. Phys. Chem., 1980, 84, 2088 CrossRef CAS.
  20. A. J. Elliot and F. C. Sopchyshyn, Int. J. Chem. Kinet., 1984, 16, 1247 CrossRef CAS.
  21. V. Nagarajan and R. W. Fessenden, J. Phys. Chem., 1985, 89, 2330 CrossRef CAS.
  22. G. V. Buxton and C. R. Stuart, J. Chem. Soc., Faraday Trans., 1995, 91, 279 RSC.
  23. Y. Hirao, H. Ogawa, S. Yamada, Y. Sato, T. Yamada, T. Murakami, A. Kitagawa, K. Sato, A. Itano, M. Kumada, E. Takada, M. Kanazawa, K. Noda, M. Sudou, K. Kawachi, F. Soga, M. Endo, T. Kanai, S. Minohara, H. Koyama-Ito and T. Kohno, Heavy Ion Medical Accelerator in Chiba, A Design Summary and Update, NIRS-M-89, HIMAC-001, 1992 Search PubMed.
  24. J. W. T. Spinks and R. J. Woods, An Introduction to Radiation Chemistry, 3rd edn, Wiley, New York, 1990 Search PubMed.
  25. H. Kudoh, T. Sasuga, T. Seguchi and Y. Katsumura, Polymer, 1996, 37, 2903 CrossRef CAS.
  26. H. Kobayashi and Y. Tabata, Radiat. Phys. Chem., 1989, 34, 447 CrossRef.
  27. G. V. Buxton, C. L. Greenstock, W. P. Helman and A. B. Ross, J. Phys. Chem. Ref. Data, 1988, 17, 513 CAS.
  28. Z. D. Draganic and I. G. Draganic, J. Phys. Chem., 1973, 77, 765 CrossRef CAS.
  29. R. H. Schuler and B. Behar, Proc. 5th Tihany Symp. on Radiation Chemistry, ed. J. Dobo, P. Hedvig and R. Schiller, Akademai Kiado, Budapest, 1983, vol. 1, p. 183 Search PubMed.
  30. A. R. Anderson and E. J. Hart, Radiat. Res., 1961, 14, 689 CAS.
  31. A. J. Elliot, M. P. Chenier, D. C. Ouellette and V. T. Koslowsky, J. Phys. Chem., 1996, 100, 9014 CrossRef CAS.
  32. A. Appleby and H. A. Schwarz, J. Phys. Chem., 1969, 73, 1937 CrossRef CAS.
  33. A. B. Ross, W. G. Mallard, W. P. Helman, G. V. Buxton, R. E. Huie and P. Neta, NDRL-NIST Solution Kinetics Database, version 2.0, National Institute of Standards and Technology, Gaithersburg, MD, 1994 Search PubMed.
  34. W. G. Burns, H. E. Sims and J. A. B. Goodall, Radiat. Phys. Chem., 1984, 23, 143 CAS.
  35. S. M. Pimblott and J. A. LaVerne, J. Phys. Chem., 1994, 98, 6136 CrossRef CAS.
  36. A. J. Elliot, S. Geertsen and G. V. Buxton, J. Chem. Soc., Faraday Trans. 1, 1988, 84, 1101 RSC.
  37. G. V. Buxton, Trans. Faraday Soc., 1969, 65, 2150 RSC.
  38. S. Gordon, E. J. Hart, M. S. Matheson, J. Rabani and J. K. Thomas, Discuss. Faraday Soc., 1963, 36, 193 RSC.
  39. H. A. Schwarz, J. Phys. Chem., 1992, 96, 8937 CrossRef CAS.
  40. B. H. J. Bielski and H. W. Richter, J. Am. Chem. Soc., 1977, 99, 3019 CrossRef CAS.
  41. Q. G. Mulazzani, M. D'Angelantonio, M. Venturi, M. Z. Hoffman and M. A. J. Rodgers, J. Phys. Chem., 1986, 90, 5347 CrossRef CAS.
  42. G. V. Buxton, R. M. Sellers and D. R. McCracken, J. Chem. Soc., Faraday Trans. 1, 1976, 72, 1464 RSC.
  43. J. P. Keene, Y. Raef and A. J. Swallow, in Pulse Radiolysis, ed. M. Ebert, J. P. Keene, A. J. Swallow and J. H. Baxendale, Academic Press, London, 1965, p. 99 Search PubMed.
  44. N. Chitose, Y. Katsumura, M. Domae and K. Ishigure, in Proc. of the 38th Annual Meeting on the Radiation Chemistry in Japan, ed. K. Shinsaka, Jpn. Soc. Radiat. Chem., Kanazawa, Japan, 1995, pp. 55–56 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.