Asymmetric functionalisation of the benzylic methylene group in tricarbonylchromium(0) complexes of alkyl benzyl ethers[(PhCH2OR)(CO)3Cr0] is achived in high yield (86–96%) and high enantiomeric excess (ee)(97 to ![[gt-or-equal]](https://www.rsc.org/images/entities/char_2a7e.gif)
99%) using chiral base methodology.
E. L. M. Cowton, S. E. Gibson (née Thomas), M. J. Schneider and M. H. Smith, Chem. Commun., 1996, 839 DOI: 10.1039/CC9960000839
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