Reaction of cyclohexene with Ru3(CO)12 leads primarily to dehydrogenation with products based on C6H8 and C6H6, however the formation of the cluster complex Ru6(µ3-H)(µ4-η2-CO)2(CO)13(η5C5H4Me)1, has revealed that C–C activation and ring contraction is also a significant reaction pathway.
S. L. Ingham, B. F. G. Johnson, C. M. Martin and D. Parker, J. Chem. Soc., Chem. Commun., 1995, 159 DOI: 10.1039/C39950000159
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