Issue 2, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Ester elimination versus ligand exchange: the role of the solvent in tin–oxo cluster-building reactions

James Caruso,   Mark J. Hampden-Smith,   Arnold L. Rheingold  and  Glenn Yap  

Abstract

Ester elimination between Sn(OBUt)4 and Sn(OAc)4 in refluxing toluene yields Sn6(O)6(OCMe3)6(O2CMe)6 which is characterized in solution and in the solid state by single-crystal X-ray diffraction; reaction of the same species in pyridine results in the formation of the ligand exchange products, Sn(OBut)X(OAc)4–x where x= 1–3.

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Article information

DOI
https://doi.org/10.1039/C39950000157
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 157-158

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Ester elimination versus ligand exchange: the role of the solvent in tin–oxo cluster-building reactions

J. Caruso, M. J. Hampden-Smith, A. L. Rheingold and G. Yap, J. Chem. Soc., Chem. Commun., 1995, 157 DOI: 10.1039/C39950000157

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