Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: novel donor–acceptor heterobimetallic materials
Abstract
Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5){C5H4C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif) C[Os(dppm)2Cl]}][dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal–metal interaction via the conjugated ligand group.
C[Os(dppm)2Cl]}][dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal–metal interaction via the conjugated ligand group.
 
                



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