Arsine complexes of rhodium(I) efficiently catalyze the transfer dehydrogenation of alkenes under an atmosphere of hydrogen, while at the same time producing decreased levels of ‘direct hydrogenated’ sacrificaial olefin relative to that derived from similar phosphine-based catalysts.
J. A. Miller and L. K. Knox, J. Chem. Soc., Chem. Commun., 1994, 1449 DOI: 10.1039/C39940001449
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