The rearrangement of methylmalonyl to succinyl radicals becomes an efficient process, when the reaction is performed in a protic solvent with both the vitamin B12-derived catalyst and the substrate carrying a C18 instead of a C2 alkyl chain.
A. Wolleb-Gygi, T. Darbre, V. Siljegovic and R. Keese, J. Chem. Soc., Chem. Commun., 1994, 835 DOI: 10.1039/C39940000835
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