Starting from 1,5-diaminopentane as template it is possible to produce a novel microporous layered aluminophosphate (Al:P = 0.75) in which there are two distinct kinds of eight-membered rings within the layers: those that are approximately circular (diameter 7.0 Å) accommodate piperidinium ions, while the elliptical ones (ca. 5.9–8.0 Å) contain 1,5-diammoniumpentane ions.
R. H. Jones, A. M. Chippindale, S. Natarajan and J. M. Thomas, J. Chem. Soc., Chem. Commun., 1994, 565 DOI: 10.1039/C39940000565
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